Springer Nature
Catalysis Letters
,  volume 121 ,  issue 3-4 ,  pages 199-208

Reductive Dehydration of Ethanol: A New Route Towards Alkanes

Publication type: Journal Article
Publication date: 2007-12-04
Springer Nature
scimago Q2
wos Q3
SJR: 0.539
CiteScore: 4.9
Impact factor: 2.4
ISSN: 1011372X, 1572879X
General Chemistry
Catalysis
Abstract
New reactions, catalytic ethanol reductive dehydration into alkanes C3–C10 and cross-coupling of ethanol with cyclopentanol into alkyl substituted cycloalkanes, were studied. The reductive dehydration of ethanol was carried out at 350 °C and 50 atm of Ar. The intermetallic hydrides with different hydrogen content, industrial Pt/γ-Al2O3 and reduced molten promoted iron catalysts were used as catalysts. The yield of alkanes varies depending on acid/base additives. The conversion of ethanol and the yield of higher alkanes increase as the hydrogen content in the intermetallic material decreases. When MgO is used as additive ethanol converts mainly into iso-alkanes. The content of iso-alkanes in the C5–C10 fraction reaches 92%. The cross-coupling of ethanol with cyclopentanol over the catalytic compositions consisting of intermetallic hydride and Pt/γ-Al2O3 and reduced molten promoted iron afforded cyclic alkyl substituted hydrocarbons.
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Tsodikov M. V. et al. Reductive Dehydration of Ethanol: A New Route Towards Alkanes // Catalysis Letters. 2007. Vol. 121. No. 3-4. pp. 199-208.
GOST all authors (up to 50) Copy
Tsodikov M. V., Yandieva F. A., Kugel V., Chistyakov A. V., Gekhman A. E., Moiseev I. I. Reductive Dehydration of Ethanol: A New Route Towards Alkanes // Catalysis Letters. 2007. Vol. 121. No. 3-4. pp. 199-208.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1007/s10562-007-9347-7
UR - https://doi.org/10.1007/s10562-007-9347-7
TI - Reductive Dehydration of Ethanol: A New Route Towards Alkanes
T2 - Catalysis Letters
AU - Tsodikov, M V
AU - Yandieva, F A
AU - Kugel, V.Ya.
AU - Chistyakov, A. V.
AU - Gekhman, A E
AU - Moiseev, I. I.
PY - 2007
DA - 2007/12/04
PB - Springer Nature
SP - 199-208
IS - 3-4
VL - 121
SN - 1011-372X
SN - 1572-879X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2007_Tsodikov,
author = {M V Tsodikov and F A Yandieva and V.Ya. Kugel and A. V. Chistyakov and A E Gekhman and I. I. Moiseev},
title = {Reductive Dehydration of Ethanol: A New Route Towards Alkanes},
journal = {Catalysis Letters},
year = {2007},
volume = {121},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007/s10562-007-9347-7},
number = {3-4},
pages = {199--208},
doi = {10.1007/s10562-007-9347-7}
}
MLA
Cite this
MLA Copy
Tsodikov, M. V., et al. “Reductive Dehydration of Ethanol: A New Route Towards Alkanes.” Catalysis Letters, vol. 121, no. 3-4, Dec. 2007, pp. 199-208. https://doi.org/10.1007/s10562-007-9347-7.