Springer Nature
Catalysis Letters
,  volume 148 ,  issue 5 ,  pages 1472-1477

Mono and Bimetallic Pt–(M)/Al2O3 Catalysts for Dehydrogenation of Perhydro-N-ethylcarbazole as the Second Stage of Hydrogen Storage

Publication type: Journal Article
Publication date: 2018-03-07
Springer Nature
scimago Q2
wos Q3
SJR: 0.539
CiteScore: 4.9
Impact factor: 2.4
ISSN: 1011372X, 1572879X
General Chemistry
Catalysis
Abstract
The comparative study of the activity of mono- and bimetallic Pt–(M)/Al2O3 catalysts in perhydro-N-ethylcarbazole dehydrogenation as the second stage of hydrogen storage (hydrogen release) has been performed. It has been found that the activity of a Pt/Al2O3 catalyst can be enhanced via the second metal (Cr, Pd) introduction. This fact gives the possibility to use Pt–(M)/Al2O3 catalysts for the hydrogen storage process based on reversible cycles of hydrogenation–dehydrogenation of aromatic substrates. X-ray absorption spectroscopy (XANES and EXAFS) revealed that Cr introduction impacts the electronic state and local environment of Pt. The average size of platinum metal nanoparticles is about two times smaller in Pt–Cr/Al2O3 compared to Pt/Al2O3.
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GOST |
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GOST Copy
Tarasov A. L. et al. Mono and Bimetallic Pt–(M)/Al2O3 Catalysts for Dehydrogenation of Perhydro-N-ethylcarbazole as the Second Stage of Hydrogen Storage // Catalysis Letters. 2018. Vol. 148. No. 5. pp. 1472-1477.
GOST all authors (up to 50) Copy
Tarasov A. L., Tkachenko O. P., KUSTOV L. M. Mono and Bimetallic Pt–(M)/Al2O3 Catalysts for Dehydrogenation of Perhydro-N-ethylcarbazole as the Second Stage of Hydrogen Storage // Catalysis Letters. 2018. Vol. 148. No. 5. pp. 1472-1477.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1007/s10562-018-2325-4
UR - https://doi.org/10.1007/s10562-018-2325-4
TI - Mono and Bimetallic Pt–(M)/Al2O3 Catalysts for Dehydrogenation of Perhydro-N-ethylcarbazole as the Second Stage of Hydrogen Storage
T2 - Catalysis Letters
AU - Tarasov, Andrey L
AU - Tkachenko, Olga P
AU - KUSTOV, LEONID M.
PY - 2018
DA - 2018/03/07
PB - Springer Nature
SP - 1472-1477
IS - 5
VL - 148
SN - 1011-372X
SN - 1572-879X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Tarasov,
author = {Andrey L Tarasov and Olga P Tkachenko and LEONID M. KUSTOV},
title = {Mono and Bimetallic Pt–(M)/Al2O3 Catalysts for Dehydrogenation of Perhydro-N-ethylcarbazole as the Second Stage of Hydrogen Storage},
journal = {Catalysis Letters},
year = {2018},
volume = {148},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/s10562-018-2325-4},
number = {5},
pages = {1472--1477},
doi = {10.1007/s10562-018-2325-4}
}
MLA
Cite this
MLA Copy
Tarasov, Andrey L., et al. “Mono and Bimetallic Pt–(M)/Al2O3 Catalysts for Dehydrogenation of Perhydro-N-ethylcarbazole as the Second Stage of Hydrogen Storage.” Catalysis Letters, vol. 148, no. 5, Mar. 2018, pp. 1472-1477. https://doi.org/10.1007/s10562-018-2325-4.