Vinylation of cellulose in superbase catalytic systems: towards new biodegradable polymer materials
Publication type: Journal Article
Publication date: 2013-03-01
scimago Q1
wos Q1
SJR: 0.964
CiteScore: 9.8
Impact factor: 4.8
ISSN: 09690239, 1572882X
Polymers and Plastics
Abstract
Diverse celluloses including non-mercerized and mercerized ones have been successfully vinylated with acetylene in the superbase catalytic systems MOH/DMSO and MOH/THF (M = Na, K) at 85–140 °C. Depending on the reaction conditions, degree of substitution of the hydroxyl groups by highly reactive polymerazable vinyloxy groups ranges 0.11–1.22, the yields of vinylated celluloses (insoluble in water, but soluble in DMSO) being 41–89 %. Vinylated celluloses are easily decomposed under the action of white rot fungi: Phanerochaete chrysosporium, Trametes versicolor and Trametes hirsutus, and can constitute a basis for the preparation of biodegradable polymer materials (due to polymerization or polyaddition at the vinyloxy group).
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GOST
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Trofimov B. A. et al. Vinylation of cellulose in superbase catalytic systems: towards new biodegradable polymer materials // Cellulose. 2013. Vol. 20. No. 3. pp. 1201-1214.
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Trofimov B. A., Oparina L. A., Parshina L. N., Khil'ko M. Y., Tantsyrev A. P., Aleksandrova G. P. Vinylation of cellulose in superbase catalytic systems: towards new biodegradable polymer materials // Cellulose. 2013. Vol. 20. No. 3. pp. 1201-1214.
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RIS
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TY - JOUR
DO - 10.1007/s10570-013-9890-x
UR - https://doi.org/10.1007/s10570-013-9890-x
TI - Vinylation of cellulose in superbase catalytic systems: towards new biodegradable polymer materials
T2 - Cellulose
AU - Trofimov, Boris A.
AU - Oparina, Ludmila A.
AU - Parshina, Lidiya N
AU - Khil'ko, Marina Ya.
AU - Tantsyrev, Anatolii P
AU - Aleksandrova, Galina P.
PY - 2013
DA - 2013/03/01
PB - Springer Nature
SP - 1201-1214
IS - 3
VL - 20
SN - 0969-0239
SN - 1572-882X
ER -
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BibTex (up to 50 authors)
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@article{2013_Trofimov,
author = {Boris A. Trofimov and Ludmila A. Oparina and Lidiya N Parshina and Marina Ya. Khil'ko and Anatolii P Tantsyrev and Galina P. Aleksandrova},
title = {Vinylation of cellulose in superbase catalytic systems: towards new biodegradable polymer materials},
journal = {Cellulose},
year = {2013},
volume = {20},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/s10570-013-9890-x},
number = {3},
pages = {1201--1214},
doi = {10.1007/s10570-013-9890-x}
}
Cite this
MLA
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Trofimov, Boris A., et al. “Vinylation of cellulose in superbase catalytic systems: towards new biodegradable polymer materials.” Cellulose, vol. 20, no. 3, Mar. 2013, pp. 1201-1214. https://doi.org/10.1007/s10570-013-9890-x.