Reaction of 2-pyridyllithium with azine N-oxides. Simple and convenient method for the synthesis of 2,2′-bipyridine 1-oxide and 2,2′:6′,2″:6″2′″-tetrapyridine 1′-oxide
Тип публикации: Journal Article
Дата публикации: 2009-02-01
SCImago Q3
WOS Q3
БС3
SJR: 0.281
CiteScore: 2.7
Impact factor: 1.2
ISSN: 00093122, 15738353
Organic Chemistry
Краткое описание
In the reaction of 2-pyridyllithium with quinoline 1-oxide and isoquinoline 2-oxide a nucleophilic substitution of hydrogen occurs to form the corresponding pyridin-2-ylquinolines. A dimerization of the substrate occurs with pyridine 1-oxide, 2,2′-bipyridine 1-oxide or quinoxaline N-oxide. A similar dimerization in good yield occurs when treating azine N-oxides with tert-butyllithium and this serves as a simple and convenient method for preparing bi- and tetrapyridines.
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Kovalev I. S. et al. Reaction of 2-pyridyllithium with azine N-oxides. Simple and convenient method for the synthesis of 2,2′-bipyridine 1-oxide and 2,2′:6′,2″:6″2′″-tetrapyridine 1′-oxide // Chemistry of Heterocyclic Compounds. 2009. Vol. 45. No. 2. pp. 176-181.
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Kovalev I. S., Rusinov V. L., Chupakhin O. Reaction of 2-pyridyllithium with azine N-oxides. Simple and convenient method for the synthesis of 2,2′-bipyridine 1-oxide and 2,2′:6′,2″:6″2′″-tetrapyridine 1′-oxide // Chemistry of Heterocyclic Compounds. 2009. Vol. 45. No. 2. pp. 176-181.
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TY - JOUR
DO - 10.1007/s10593-009-0247-1
UR - https://doi.org/10.1007/s10593-009-0247-1
TI - Reaction of 2-pyridyllithium with azine N-oxides. Simple and convenient method for the synthesis of 2,2′-bipyridine 1-oxide and 2,2′:6′,2″:6″2′″-tetrapyridine 1′-oxide
T2 - Chemistry of Heterocyclic Compounds
AU - Kovalev, I S
AU - Rusinov, V L
AU - Chupakhin, O.N.
PY - 2009
DA - 2009/02/01
PB - Springer Nature
SP - 176-181
IS - 2
VL - 45
SN - 0009-3122
SN - 1573-8353
ER -
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@article{2009_Kovalev,
author = {I S Kovalev and V L Rusinov and O.N. Chupakhin},
title = {Reaction of 2-pyridyllithium with azine N-oxides. Simple and convenient method for the synthesis of 2,2′-bipyridine 1-oxide and 2,2′:6′,2″:6″2′″-tetrapyridine 1′-oxide},
journal = {Chemistry of Heterocyclic Compounds},
year = {2009},
volume = {45},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007/s10593-009-0247-1},
number = {2},
pages = {176--181},
doi = {10.1007/s10593-009-0247-1}
}
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MLA
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Kovalev, I. S., et al. “Reaction of 2-pyridyllithium with azine N-oxides. Simple and convenient method for the synthesis of 2,2′-bipyridine 1-oxide and 2,2′:6′,2″:6″2′″-tetrapyridine 1′-oxide.” Chemistry of Heterocyclic Compounds, vol. 45, no. 2, Feb. 2009, pp. 176-181. https://doi.org/10.1007/s10593-009-0247-1.
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