Chemistry of Heterocyclic Compounds, volume 49, issue 12, pages 1740-1747
Synthesis, spectral-luminescent properties, and photostability of Zn(II) complexes with dipyrrins modified by the periphery and meso-spacer
Publication type: Journal Article
Publication date: 2014-02-26
Journal:
Chemistry of Heterocyclic Compounds
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.5
ISSN: 00093122, 15738353
Organic Chemistry
Abstract
A comparative spectral-luminescent characterization was performed for the homoleptic zinc(II) chelates with dipyrrins containing four methyl or aryl substituents in the pyrrole rings and methine group or nitrogen atom as meso-spacer. It was shown that zinc dipyrrinates with substituted pyrrole rings and a methene spacer exhibited an intense fluorescence in nonpolar media. The phenyl-substituted complex had an order of magnitude stronger fluorescence than the methyl-substituted analog. Changing from a methene spacer to a nitrogen atom caused a substantial (up to 64 nm) red shift of the electronic absorption spectrum, and the chelate completely lost its fluorescent properties. The effects of the chelate ligand structure on the photostability of zinc(II) complexes were established.
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Dudina N. A. et al. Synthesis, spectral-luminescent properties, and photostability of Zn(II) complexes with dipyrrins modified by the periphery and meso-spacer // Chemistry of Heterocyclic Compounds. 2014. Vol. 49. No. 12. pp. 1740-1747.
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Dudina N. A., Nikonova A. Yu., Antina Y. V., Berezin M. B., Vyugin A. I. Synthesis, spectral-luminescent properties, and photostability of Zn(II) complexes with dipyrrins modified by the periphery and meso-spacer // Chemistry of Heterocyclic Compounds. 2014. Vol. 49. No. 12. pp. 1740-1747.
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TY - JOUR
DO - 10.1007/s10593-014-1426-2
UR - https://doi.org/10.1007%2Fs10593-014-1426-2
TI - Synthesis, spectral-luminescent properties, and photostability of Zn(II) complexes with dipyrrins modified by the periphery and meso-spacer
T2 - Chemistry of Heterocyclic Compounds
AU - Dudina, N A
AU - Berezin, M B
AU - Nikonova, A Yu
AU - Antina, Ye V
AU - Vyugin, A I
PY - 2014
DA - 2014/02/26 00:00:00
PB - Springer Nature
SP - 1740-1747
IS - 12
VL - 49
SN - 0009-3122
SN - 1573-8353
ER -
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@article{2014_Dudina,
author = {N A Dudina and M B Berezin and A Yu Nikonova and Ye V Antina and A I Vyugin},
title = {Synthesis, spectral-luminescent properties, and photostability of Zn(II) complexes with dipyrrins modified by the periphery and meso-spacer},
journal = {Chemistry of Heterocyclic Compounds},
year = {2014},
volume = {49},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007%2Fs10593-014-1426-2},
number = {12},
pages = {1740--1747},
doi = {10.1007/s10593-014-1426-2}
}
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Dudina, N. A., et al. “Synthesis, spectral-luminescent properties, and photostability of Zn(II) complexes with dipyrrins modified by the periphery and meso-spacer.” Chemistry of Heterocyclic Compounds, vol. 49, no. 12, Feb. 2014, pp. 1740-1747. https://doi.org/10.1007%2Fs10593-014-1426-2.