Reactions of Malonothioamide Derivatives with Azides*
Publication type: Journal Article
Publication date: 2014-09-14
scimago Q4
wos Q4
SJR: 0.243
CiteScore: 2.7
Impact factor: 1.0
ISSN: 00093122, 15738353
Organic Chemistry
Abstract
The reactions of primary and tertiary malonothioamides with aryl and sulfonyl azides can take place in three directions, depending on the nature of the thioamides and azides. Ethoxycarbonylthioacetamide reacts with aryl azides with the formation of ethyl 5-amino-1-aryl-1,2,3-triazole-4-carboxylates. In reaction with aryl azides tertiary thioamides of cyanoacetic acid form 5-amino-1-aryl-1,2,3-triazole-4-carbothioamides, and in reaction with tosyl azide they form 5-amino-4-carboxamidino-1,2,3-thia-diazoles. Hypothetical mechanisms for the transformations are discussed.
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Citations from 2024:
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Dianova L. N. et al. Reactions of Malonothioamide Derivatives with Azides* // Chemistry of Heterocyclic Compounds. 2014. Vol. 50. No. 7. pp. 972-978.
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Dianova L. N., Berseneva V. S., Eltsov O. S., Fan Z. J., Bakulev V. A. Reactions of Malonothioamide Derivatives with Azides* // Chemistry of Heterocyclic Compounds. 2014. Vol. 50. No. 7. pp. 972-978.
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TY - JOUR
DO - 10.1007/s10593-014-1552-x
UR - https://doi.org/10.1007/s10593-014-1552-x
TI - Reactions of Malonothioamide Derivatives with Azides*
T2 - Chemistry of Heterocyclic Compounds
AU - Dianova, L N
AU - Berseneva, V S
AU - Eltsov, O S
AU - Fan, Z J
AU - Bakulev, V A
PY - 2014
DA - 2014/09/14
PB - Springer Nature
SP - 972-978
IS - 7
VL - 50
SN - 0009-3122
SN - 1573-8353
ER -
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BibTex (up to 50 authors)
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@article{2014_Dianova,
author = {L N Dianova and V S Berseneva and O S Eltsov and Z J Fan and V A Bakulev},
title = {Reactions of Malonothioamide Derivatives with Azides*},
journal = {Chemistry of Heterocyclic Compounds},
year = {2014},
volume = {50},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/s10593-014-1552-x},
number = {7},
pages = {972--978},
doi = {10.1007/s10593-014-1552-x}
}
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MLA
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Dianova, L. N., et al. “Reactions of Malonothioamide Derivatives with Azides*.” Chemistry of Heterocyclic Compounds, vol. 50, no. 7, Sep. 2014, pp. 972-978. https://doi.org/10.1007/s10593-014-1552-x.