Synthesis of 3-Silylated 3-Sulfolenes from Propargylsilanes and their Reductive Desulfitation
Publication type: Journal Article
Publication date: 2021-01-01
scimago Q4
wos Q4
SJR: 0.243
CiteScore: 2.7
Impact factor: 1.0
ISSN: 00093122, 15738353
Organic Chemistry
Abstract
Protonation of propargylsilanes induces 1,2-silyl group shift and provides 2-silylated dienes. If this reaction is performed in liquid SO2, the diene formation is followed by instant cheletropic SO2 addition, and 3-silylated 3-sulfolenes are obtained. Liquid SO2 as polar and Lewis acidic reaction medium makes it possible to use relatively weak Brønsted acid catalysts such as H2O and benzoic acid. Depending on the starting material, reductive desulfitation of 3-silylated 3-sulfolenes provides vinyl, allyl, or aliphatic silanes.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Advanced Synthesis and Catalysis
2 publications, 33.33%
|
|
|
MolBank
1 publication, 16.67%
|
|
|
Organic Letters
1 publication, 16.67%
|
|
|
Journal of Organic Chemistry
1 publication, 16.67%
|
|
|
Russian Chemical Reviews
1 publication, 16.67%
|
|
|
1
2
|
Publishers
|
1
2
|
|
|
Wiley
2 publications, 33.33%
|
|
|
American Chemical Society (ACS)
2 publications, 33.33%
|
|
|
MDPI
1 publication, 16.67%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 16.67%
|
|
|
1
2
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
6
Total citations:
6
Citations from 2024:
2
(33.33%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Beļaunieks R. et al. Synthesis of 3-Silylated 3-Sulfolenes from Propargylsilanes and their Reductive Desulfitation // Chemistry of Heterocyclic Compounds. 2021. Vol. 57. No. 1. pp. 20-25.
GOST all authors (up to 50)
Copy
Beļaunieks R., Puriņš M., Kumpins V., Turks M. Synthesis of 3-Silylated 3-Sulfolenes from Propargylsilanes and their Reductive Desulfitation // Chemistry of Heterocyclic Compounds. 2021. Vol. 57. No. 1. pp. 20-25.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s10593-021-02862-1
UR - https://doi.org/10.1007/s10593-021-02862-1
TI - Synthesis of 3-Silylated 3-Sulfolenes from Propargylsilanes and their Reductive Desulfitation
T2 - Chemistry of Heterocyclic Compounds
AU - Beļaunieks, Rūdolfs
AU - Puriņš, Mikus
AU - Kumpins, Viktors
AU - Turks, Māris
PY - 2021
DA - 2021/01/01
PB - Springer Nature
SP - 20-25
IS - 1
VL - 57
SN - 0009-3122
SN - 1573-8353
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Beļaunieks,
author = {Rūdolfs Beļaunieks and Mikus Puriņš and Viktors Kumpins and Māris Turks},
title = {Synthesis of 3-Silylated 3-Sulfolenes from Propargylsilanes and their Reductive Desulfitation},
journal = {Chemistry of Heterocyclic Compounds},
year = {2021},
volume = {57},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/s10593-021-02862-1},
number = {1},
pages = {20--25},
doi = {10.1007/s10593-021-02862-1}
}
Cite this
MLA
Copy
Beļaunieks, Rūdolfs, et al. “Synthesis of 3-Silylated 3-Sulfolenes from Propargylsilanes and their Reductive Desulfitation.” Chemistry of Heterocyclic Compounds, vol. 57, no. 1, Jan. 2021, pp. 20-25. https://doi.org/10.1007/s10593-021-02862-1.