Radiolysis of aqueous solutions of poly(ethylene oxide) at 77 K
Publication type: Journal Article
Publication date: 2005-07-26
scimago Q4
wos Q4
SJR: 0.178
CiteScore: 0.9
Impact factor: 0.6
ISSN: 00181439, 16083148
Physical and Theoretical Chemistry
Abstract
Low-temperature (77 K) γ-radiolysis of aqueous solutions of poly(ethylene oxide) was studied by ESR spectroscopy. Trapped electrons, hydroxyl radicals, and -CH2-ĊH-O- radicals were identified as principal paramagnetic products of radiolysis. It was shown that an increase in the polymer concentration in solution led to a growth in number of trapped electrons and -CH2-ĊH-O- macroradicals. The decay of hydroxyl radicals occurring at 110–115 K was accompanied by the formation of -CH2-ĊH-O- macroradicals and partial recombination of hydroxyl radicals. Action of visible light resulted in virtually quantitative transformation of trapped electrons into -CH2-ĊH-O- macroradicals. The radiation-chemical yields of the species trapped at 77 K were estimated and the scheme of radiation-induced chemical processes was suggested.
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Total citations:
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GOST
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Zakurdaeva O. A. et al. Radiolysis of aqueous solutions of poly(ethylene oxide) at 77 K // High Energy Chemistry. 2005. Vol. 39. No. 4. pp. 201-206.
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Zakurdaeva O. A., Nesterov S., Feldman V. I. Radiolysis of aqueous solutions of poly(ethylene oxide) at 77 K // High Energy Chemistry. 2005. Vol. 39. No. 4. pp. 201-206.
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RIS
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TY - JOUR
DO - 10.1007/s10733-005-0042-1
UR - http://link.springer.com/10.1007/s10733-005-0042-1
TI - Radiolysis of aqueous solutions of poly(ethylene oxide) at 77 K
T2 - High Energy Chemistry
AU - Zakurdaeva, O A
AU - Nesterov, S.V.
AU - Feldman, V I
PY - 2005
DA - 2005/07/26
PB - Springer Nature
SP - 201-206
IS - 4
VL - 39
SN - 0018-1439
SN - 1608-3148
ER -
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BibTex (up to 50 authors)
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@article{2005_Zakurdaeva,
author = {O A Zakurdaeva and S.V. Nesterov and V I Feldman},
title = {Radiolysis of aqueous solutions of poly(ethylene oxide) at 77 K},
journal = {High Energy Chemistry},
year = {2005},
volume = {39},
publisher = {Springer Nature},
month = {jul},
url = {http://link.springer.com/10.1007/s10733-005-0042-1},
number = {4},
pages = {201--206},
doi = {10.1007/s10733-005-0042-1}
}
Cite this
MLA
Copy
Zakurdaeva, O. A., et al. “Radiolysis of aqueous solutions of poly(ethylene oxide) at 77 K.” High Energy Chemistry, vol. 39, no. 4, Jul. 2005, pp. 201-206. http://link.springer.com/10.1007/s10733-005-0042-1.
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