Synthesis and inclusion properties of pillar[n]arenes
Yuhui Kou
1
,
Derong Cao
1
,
Hongqi Tao
1
,
Lingyun Wang
1
,
Jianquan Liang
1
,
Zhizhao Chen
1
,
Herbert Meier
2
Publication type: Journal Article
Publication date: 2012-09-02
scimago Q3
wos Q3
SJR: 0.364
CiteScore: 3.7
Impact factor: 1.6
ISSN: 13883127, 15731111, 09230750
General Chemistry
Condensed Matter Physics
Food Science
Abstract
A detailed study of the reaction conditions revealed that a quantitative cyclocondensation of 1,4-dialkoxy-2,5-bis(alkoxymethyl)-benzenes to pillar[n]arenes can be achieved by catalysis of p-toluenesulfonic acid in CH2Cl2. Major product of this new reaction is in each case a cyclopentamer (n = 5), but small amounts of the pillar[n]arenes with n = 6, 7 and 10 can be obtained as well. Different alkoxy groups in 1- and 4-position lead to regioisomers. All cyclooligomers exist in pillar structures as pair of enantiomers, which show a racemisation at room temperature, which is fast in terms of the NMR time scale. The racemisation process occurs by rotation of the 1,4-phenylene segments in the macrocyclic rings. Pillar[n]arenes exhibit novel host–guest behavior.
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18
Total citations:
18
Citations from 2024:
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(11%)
The most citing journal
Citations in journal:
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GOST
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Kou Y. et al. Synthesis and inclusion properties of pillar[n]arenes // Journal of Inclusion Phenomena and Macrocyclic Chemistry. 2012. Vol. 77. No. 1-4. pp. 279-289.
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Kou Y., Cao D., Tao H., Wang L., Liang J., Chen Z., Meier H. Synthesis and inclusion properties of pillar[n]arenes // Journal of Inclusion Phenomena and Macrocyclic Chemistry. 2012. Vol. 77. No. 1-4. pp. 279-289.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s10847-012-0242-5
UR - https://doi.org/10.1007/s10847-012-0242-5
TI - Synthesis and inclusion properties of pillar[n]arenes
T2 - Journal of Inclusion Phenomena and Macrocyclic Chemistry
AU - Kou, Yuhui
AU - Cao, Derong
AU - Tao, Hongqi
AU - Wang, Lingyun
AU - Liang, Jianquan
AU - Chen, Zhizhao
AU - Meier, Herbert
PY - 2012
DA - 2012/09/02
PB - Springer Nature
SP - 279-289
IS - 1-4
VL - 77
SN - 1388-3127
SN - 1573-1111
SN - 0923-0750
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Kou,
author = {Yuhui Kou and Derong Cao and Hongqi Tao and Lingyun Wang and Jianquan Liang and Zhizhao Chen and Herbert Meier},
title = {Synthesis and inclusion properties of pillar[n]arenes},
journal = {Journal of Inclusion Phenomena and Macrocyclic Chemistry},
year = {2012},
volume = {77},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/s10847-012-0242-5},
number = {1-4},
pages = {279--289},
doi = {10.1007/s10847-012-0242-5}
}
Cite this
MLA
Copy
Kou, Yuhui, et al. “Synthesis and inclusion properties of pillar[n]arenes.” Journal of Inclusion Phenomena and Macrocyclic Chemistry, vol. 77, no. 1-4, Sep. 2012, pp. 279-289. https://doi.org/10.1007/s10847-012-0242-5.