Molecular optical filtering in perovskite solar cells
Publication type: Journal Article
Publication date: 2022-02-23
scimago Q2
wos Q2
SJR: 0.529
CiteScore: 5.1
Impact factor: 2.8
ISSN: 09574522, 1573482X
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Electrical and Electronic Engineering
Abstract
In this paper, we investigate the applicability of a vacuum-deposited layer of porphyrazine [series] pigment, the tris(1,2,5-thiadiazolo)subporphyrazinatoboron(III) chloride (SubPzS3), as optical filter for inverted perovskite solar cells. Thin films formed from this material are characterized by a narrow, high-intensity absorption band in the visible range, with a maximum at ~ 545 nm. The operation stability of the device was assessed by the dynamic J–V characteristics. The efficiency of solar cells equipped with such optical filter is lower due to a decrease in the total number of photons absorbed by the perovskite layer. However, their stability to photolysis by the impact of sunlight is higher and, what is more, the filtered radiation has a stabilizing effect on the performance of cells under long-term illumination. Transformation of the perovskite material in the solar cells is determined by a trade-off between destructive and healing photons that penetrate into the perovskite photoabsorber depending on whether or not it has a filtering layer.
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Travkin V. et al. Molecular optical filtering in perovskite solar cells // Journal of Materials Science: Materials in Electronics. 2022. Vol. 33. No. 10. pp. 7728-7737.
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Travkin V., Koptyaev A., Hamdoush M., Pakhomov G. Molecular optical filtering in perovskite solar cells // Journal of Materials Science: Materials in Electronics. 2022. Vol. 33. No. 10. pp. 7728-7737.
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RIS
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TY - JOUR
DO - 10.1007/s10854-022-07924-4
UR - https://doi.org/10.1007/s10854-022-07924-4
TI - Molecular optical filtering in perovskite solar cells
T2 - Journal of Materials Science: Materials in Electronics
AU - Travkin, Vlad
AU - Koptyaev, Andrey
AU - Hamdoush, Mahmoud
AU - Pakhomov, Georgy
PY - 2022
DA - 2022/02/23
PB - Springer Nature
SP - 7728-7737
IS - 10
VL - 33
SN - 0957-4522
SN - 1573-482X
ER -
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BibTex (up to 50 authors)
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@article{2022_Travkin,
author = {Vlad Travkin and Andrey Koptyaev and Mahmoud Hamdoush and Georgy Pakhomov},
title = {Molecular optical filtering in perovskite solar cells},
journal = {Journal of Materials Science: Materials in Electronics},
year = {2022},
volume = {33},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007/s10854-022-07924-4},
number = {10},
pages = {7728--7737},
doi = {10.1007/s10854-022-07924-4}
}
Cite this
MLA
Copy
Travkin, Vlad, et al. “Molecular optical filtering in perovskite solar cells.” Journal of Materials Science: Materials in Electronics, vol. 33, no. 10, Feb. 2022, pp. 7728-7737. https://doi.org/10.1007/s10854-022-07924-4.