New Synthesis Method of N-Monosubstituted Ammonium-closo-Decaborates
A P Zhdanov
1, 2
,
V V Voinova
1, 2
,
I N Klyukin
1
,
A. S. Kubasov
1
,
K Yu Zhizhin
1
,
N. T. Kuznetsov
1
Publication type: Journal Article
Publication date: 2019-07-12
scimago Q2
wos Q1
SJR: 0.515
CiteScore: 6.7
Impact factor: 3.6
ISSN: 10407278, 15728862
General Chemistry
Biochemistry
Condensed Matter Physics
General Materials Science
Abstract
In work, the process of interaction of nitrilium derivatives of the closo-decaborate anion with lithium aluminum hydride was studied. Reduction process proceeds under mild conditions and leads to the formation of N-alkylammonium-closo-decaborate with high yields and selectivity. For the structure of (NnBu4)[2-B10H9NH2CH2CH3] was confirmed by single-crystal X-ray diffraction.
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Zhdanov A. P. et al. New Synthesis Method of N-Monosubstituted Ammonium-closo-Decaborates // Journal of Cluster Science. 2019. Vol. 30. No. 5. pp. 1327-1333.
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Zhdanov A. P., Voinova V. V., Klyukin I. N., Kubasov A. S., Zhizhin K. Yu., Kuznetsov N. T. New Synthesis Method of N-Monosubstituted Ammonium-closo-Decaborates // Journal of Cluster Science. 2019. Vol. 30. No. 5. pp. 1327-1333.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s10876-019-01628-2
UR - https://doi.org/10.1007/s10876-019-01628-2
TI - New Synthesis Method of N-Monosubstituted Ammonium-closo-Decaborates
T2 - Journal of Cluster Science
AU - Zhdanov, A P
AU - Voinova, V V
AU - Klyukin, I N
AU - Kubasov, A. S.
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2019
DA - 2019/07/12
PB - Springer Nature
SP - 1327-1333
IS - 5
VL - 30
SN - 1040-7278
SN - 1572-8862
ER -
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BibTex (up to 50 authors)
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@article{2019_Zhdanov,
author = {A P Zhdanov and V V Voinova and I N Klyukin and A. S. Kubasov and K Yu Zhizhin and N. T. Kuznetsov},
title = {New Synthesis Method of N-Monosubstituted Ammonium-closo-Decaborates},
journal = {Journal of Cluster Science},
year = {2019},
volume = {30},
publisher = {Springer Nature},
month = {jul},
url = {https://doi.org/10.1007/s10876-019-01628-2},
number = {5},
pages = {1327--1333},
doi = {10.1007/s10876-019-01628-2}
}
Cite this
MLA
Copy
Zhdanov, A. P., et al. “New Synthesis Method of N-Monosubstituted Ammonium-closo-Decaborates.” Journal of Cluster Science, vol. 30, no. 5, Jul. 2019, pp. 1327-1333. https://doi.org/10.1007/s10876-019-01628-2.