Boron Cluster Anion [B12H12]2– in Zinc(II) and Cadmium(II) Complexation at the Presence of N-Donor Heterocyclic Ligands

Тип публикации: Journal Article
Дата публикации: 2022-05-16
Springer Nature
SCImago Q2
WOS Q1
БС1
SJR: 0.552
CiteScore: 6.7
Impact factor: 3.6
ISSN: 10407278, 15728862
General Chemistry
Biochemistry
Condensed Matter Physics
General Materials Science
Краткое описание
Zinc(II) and cadmium(II) complexation with the dodecahydrido-closo-dodecaborate anion [B12H12]2– in the presence of benzimidazole ligands 1-methylbenzimidazo-2-yl-methyleneaniline (L1) and 1-ethyl-2-(4-methoxyphenyl)azobenzimidazole (L2) was studied. A number of Zn(II) and Cd(II) complexes with the [B12H12]2– anion and ligands L1 or L2 were obtained and characterized. Effect of the metal nature on the composition and structure of the resulting compounds was determined. Only tris-chelate zinc(II) complexes with the [B12H12]2– anion were isolated. For cadmium, first examples of mixed-ligand complexes with the [B12H12]2– anion coordinated by the metal atom via 3c2e (CdHB) bonds were isolated. Structures of complexes [Zn(L1)3][B12H12]·2CH3CN, [Cd(L1)2[B12H12]]·2CH3CN and [Cd(L2)2(CH3CN)[B12H12]]·CH3CN were determined by X-ray diffraction.
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Korolenko S. E. et al. Boron Cluster Anion [B12H12]2– in Zinc(II) and Cadmium(II) Complexation at the Presence of N-Donor Heterocyclic Ligands // Journal of Cluster Science. 2022.
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Korolenko S. E., Kubasov A. S., Khan N. A., Goeva L. V., Burlov A. S., Divaeva L. N., Malinina E. A., Avdeeva V. V., Zhizhin K. Y., Kuznetsov N. T. Boron Cluster Anion [B12H12]2– in Zinc(II) and Cadmium(II) Complexation at the Presence of N-Donor Heterocyclic Ligands // Journal of Cluster Science. 2022.
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TY - JOUR
DO - 10.1007/s10876-022-02263-0
UR - https://doi.org/10.1007/s10876-022-02263-0
TI - Boron Cluster Anion [B12H12]2– in Zinc(II) and Cadmium(II) Complexation at the Presence of N-Donor Heterocyclic Ligands
T2 - Journal of Cluster Science
AU - Korolenko, Svetlana E
AU - Kubasov, Alexey S.
AU - Khan, Nadezhda A
AU - Goeva, Lyudmila V.
AU - Burlov, Anatoliy S.
AU - Divaeva, Lyudmila N
AU - Malinina, Elena A
AU - Avdeeva, Varvara V
AU - Zhizhin, Konstantin Yu.
AU - Kuznetsov, Nikolay T.
PY - 2022
DA - 2022/05/16
PB - Springer Nature
SN - 1040-7278
SN - 1572-8862
ER -
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@article{2022_Korolenko,
author = {Svetlana E Korolenko and Alexey S. Kubasov and Nadezhda A Khan and Lyudmila V. Goeva and Anatoliy S. Burlov and Lyudmila N Divaeva and Elena A Malinina and Varvara V Avdeeva and Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov},
title = {Boron Cluster Anion [B12H12]2– in Zinc(II) and Cadmium(II) Complexation at the Presence of N-Donor Heterocyclic Ligands},
journal = {Journal of Cluster Science},
year = {2022},
publisher = {Springer Nature},
month = {may},
url = {https://doi.org/10.1007/s10876-022-02263-0},
doi = {10.1007/s10876-022-02263-0}
}
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