Synthesis, photophysical and redox properties of the D-π-A type pyrimidine dyes bearing the 9-phenyl-9H-carbazole moiety
Тип публикации: Journal Article
Дата публикации: 2015-03-31
scimago Q3
wos Q2
БС3
SJR: 0.422
CiteScore: 5.3
Impact factor: 3.1
ISSN: 10530509, 15734994
PubMed ID:
25822191
Biochemistry
Spectroscopy
Clinical Biochemistry
Law
Sociology and Political Science
Social Sciences (miscellaneous)
Clinical Psychology
Краткое описание
Novel donor-π-acceptor dyes bearing the pyrimidine unit as an electron-withdrawing group have been synthesized by using combination of two processes, based on the microwave-assisted Suzuki cross-coupling reaction and nucleophilic aromatic substitution of hydrogen. Spectral properties of the obtained dyes in six aprotic solvents of various polarities have been studied by ultraviolet–visible and fluorescence spectroscopy. In contrast to the absorption spectra, fluorescence emission spectra displayed a strong dependence from their solvent polarities. The nature of the observed long wavelength maxima has been elucidated by means of quantum chemical calculations. The electrochemical properties of these dyes have been investigated by using cyclic voltammetry, while their photovoltaic performance was evaluated by a device fabrication study. The experimental and calculation data show that all of the dyes can be regarded as potentially good photosensitizers for dye-sensitized solar cells.
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Verbitskiy E. V. et al. Synthesis, photophysical and redox properties of the D-π-A type pyrimidine dyes bearing the 9-phenyl-9H-carbazole moiety // Journal of Fluorescence. 2015. Vol. 25. No. 3. pp. 763-775.
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Verbitskiy E. V., Schepochkin A. V., Makarova N. I., Dorogan I. V., Metelitsa A. V., Minkin V. I., Kozyukhin S. A., Emets V. V., Grindberg V. A., Nemytov A. I., Rusinov G. L., Charushin V. N. Synthesis, photophysical and redox properties of the D-π-A type pyrimidine dyes bearing the 9-phenyl-9H-carbazole moiety // Journal of Fluorescence. 2015. Vol. 25. No. 3. pp. 763-775.
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TY - JOUR
DO - 10.1007/s10895-015-1565-6
UR - https://doi.org/10.1007/s10895-015-1565-6
TI - Synthesis, photophysical and redox properties of the D-π-A type pyrimidine dyes bearing the 9-phenyl-9H-carbazole moiety
T2 - Journal of Fluorescence
AU - Verbitskiy, Egor V
AU - Schepochkin, Aleksandr V
AU - Makarova, Nadezhda I
AU - Dorogan, Igor V
AU - Metelitsa, Anatoly V
AU - Minkin, Vladimir I.
AU - Kozyukhin, Sergey A
AU - Emets, Victor V
AU - Grindberg, Vitaly A
AU - Nemytov, Alexey I.
AU - Rusinov, Gennady L.
AU - Charushin, Valery N.
PY - 2015
DA - 2015/03/31
PB - Springer Nature
SP - 763-775
IS - 3
VL - 25
PMID - 25822191
SN - 1053-0509
SN - 1573-4994
ER -
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@article{2015_Verbitskiy,
author = {Egor V Verbitskiy and Aleksandr V Schepochkin and Nadezhda I Makarova and Igor V Dorogan and Anatoly V Metelitsa and Vladimir I. Minkin and Sergey A Kozyukhin and Victor V Emets and Vitaly A Grindberg and Alexey I. Nemytov and Gennady L. Rusinov and Valery N. Charushin},
title = {Synthesis, photophysical and redox properties of the D-π-A type pyrimidine dyes bearing the 9-phenyl-9H-carbazole moiety},
journal = {Journal of Fluorescence},
year = {2015},
volume = {25},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/s10895-015-1565-6},
number = {3},
pages = {763--775},
doi = {10.1007/s10895-015-1565-6}
}
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MLA
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Verbitskiy, Egor V., et al. “Synthesis, photophysical and redox properties of the D-π-A type pyrimidine dyes bearing the 9-phenyl-9H-carbazole moiety.” Journal of Fluorescence, vol. 25, no. 3, Mar. 2015, pp. 763-775. https://doi.org/10.1007/s10895-015-1565-6.
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