Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer
Тип публикации: Journal Article
Дата публикации: 2016-08-16
SCImago Q2
WOS Q2
БС3
SJR: 0.494
CiteScore: 5.3
Impact factor: 3.1
ISSN: 10530509, 15734994
PubMed ID:
27530633
Biochemistry
Spectroscopy
Clinical Biochemistry
Law
Sociology and Political Science
Social Sciences (miscellaneous)
Clinical Psychology
Краткое описание
Two boron-dipyrrin (BODIPY) based dyes with dimethylaminophenyl and carboxyphenyl substituents in 8-position of dipyrrin ligand have been synthesized and characterized. Photophysical and spectral properties of the obtained compounds have been investigated in water-ethanol mixture and water-cyclohexane system with variation of pH values. The equilibria constants of the compounds were identified by classical methods of acid-base titration. BODIPY bearing dimethylaminophenyl and carboxyphenyl subunits show deprotonation/protonation dependent fluorescence off/on-switching. The change of the emission could be mechanistically explained by a PET (photoinduced electron transfer) from the 8-substituent to the fluorophore. The present study demonstrates that BODIPY-based fluorescent sensors can be used to measure the pH in the range of 2–13 extending the scope of BODIPY dyes available as pH-indicators. Investigated compounds demonstrate weak dye-dye interaction allowing their cooperative usage as indicators.
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27
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ГОСТ
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Marfin Yu. S. et al. Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer // Journal of Fluorescence. 2016. Vol. 26. No. 6. pp. 2105-2112.
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Marfin Yu. S., Shipalova M. V., Kurzin V. O., Ksenofontova K. V., Solomonov A. V., Rumyantsev E. V. Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer // Journal of Fluorescence. 2016. Vol. 26. No. 6. pp. 2105-2112.
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RIS
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TY - JOUR
DO - 10.1007/s10895-016-1905-1
UR - https://doi.org/10.1007/s10895-016-1905-1
TI - Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer
T2 - Journal of Fluorescence
AU - Marfin, Yu S
AU - Shipalova, M V
AU - Kurzin, V O
AU - Ksenofontova, K V
AU - Solomonov, A. V.
AU - Rumyantsev, E V
PY - 2016
DA - 2016/08/16
PB - Springer Nature
SP - 2105-2112
IS - 6
VL - 26
PMID - 27530633
SN - 1053-0509
SN - 1573-4994
ER -
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BibTex (до 50 авторов)
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@article{2016_Marfin,
author = {Yu S Marfin and M V Shipalova and V O Kurzin and K V Ksenofontova and A. V. Solomonov and E V Rumyantsev},
title = {Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer},
journal = {Journal of Fluorescence},
year = {2016},
volume = {26},
publisher = {Springer Nature},
month = {aug},
url = {https://doi.org/10.1007/s10895-016-1905-1},
number = {6},
pages = {2105--2112},
doi = {10.1007/s10895-016-1905-1}
}
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MLA
Скопировать
Marfin, Yu. S., et al. “Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer.” Journal of Fluorescence, vol. 26, no. 6, Aug. 2016, pp. 2105-2112. https://doi.org/10.1007/s10895-016-1905-1.
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