Journal of Fluorescence

, volume 26 , issue 6 , pages 2105-2112

Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer

Yu S Marfin ¹

M V Shipalova ¹

V O Kurzin ¹

K V Ksenofontova ¹

A. V. Solomonov ¹

E V Rumyantsev ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Department of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo, Russia |

Publication type: Journal Article

Publication date: 2016-08-16

Springer Nature

Journal of Fluorescence

scimago Q3

wos Q2

SJR: 0.422

CiteScore: 5.3

Impact factor: 3.1

ISSN: 10530509, 15734994

DOI: 10.1007/s10895-016-1905-1

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PubMed ID: 27530633

Biochemistry

Spectroscopy

Clinical Biochemistry

Law

Sociology and Political Science

Social Sciences (miscellaneous)

Clinical Psychology

Abstract

Two boron-dipyrrin (BODIPY) based dyes with dimethylaminophenyl and carboxyphenyl substituents in 8-position of dipyrrin ligand have been synthesized and characterized. Photophysical and spectral properties of the obtained compounds have been investigated in water-ethanol mixture and water-cyclohexane system with variation of pH values. The equilibria constants of the compounds were identified by classical methods of acid-base titration. BODIPY bearing dimethylaminophenyl and carboxyphenyl subunits show deprotonation/protonation dependent fluorescence off/on-switching. The change of the emission could be mechanistically explained by a PET (photoinduced electron transfer) from the 8-substituent to the fluorophore. The present study demonstrates that BODIPY-based fluorescent sensors can be used to measure the pH in the range of 2–13 extending the scope of BODIPY dyes available as pH-indicators. Investigated compounds demonstrate weak dye-dye interaction allowing their cooperative usage as indicators.

Found

2 citations

Ksenofontov Alexander

🥼 🤝

PhD in Chemistry

104 publications, 1 115 citations, 54 reviews

h-index: 17

G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

Research interests

Computational chemistry

Coordination Chemistry

1 citation

Churakov Andrei

PhD in Chemistry

553 publications, 7 015 citations, 13 reviews

h-index: 37

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

1 citation

Antina Elena

DSc in Chemistry

207 publications, 2 270 citations

h-index: 22

G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

1 citation

Bocharov Pavel

16 publications, 231 citations

h-index: 10

G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

1 citation

Pogonin Alexander

🥼 🤝

PhD in Chemistry

34 publications, 240 citations

h-index: 10

Ivanovo State University of Chemistry and Technology

Macroheterocyclic compounds

Porphyrins

Quantum Chemistry

Structural chemistry

1 citation

Sbytov Dmiyrii

🤝

4 publications, 86 citations

1 citation

Lebedev Maxim

8 publications, 49 citations

h-index: 4

Ivanovo State University of Chemistry and Technology

Research interests

Nanoparticles

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GOST |

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GOST Copy

Marfin Yu. S. et al. Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer // Journal of Fluorescence. 2016. Vol. 26. No. 6. pp. 2105-2112.

GOST all authors (up to 50) Copy

Marfin Yu. S., Shipalova M. V., Kurzin V. O., Ksenofontova K. V., Solomonov A. V., Rumyantsev E. V. Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer // Journal of Fluorescence. 2016. Vol. 26. No. 6. pp. 2105-2112.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1007/s10895-016-1905-1

UR - https://doi.org/10.1007/s10895-016-1905-1

TI - Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer

T2 - Journal of Fluorescence

AU - Marfin, Yu S

AU - Shipalova, M V

AU - Kurzin, V O

AU - Ksenofontova, K V

AU - Solomonov, A. V.

AU - Rumyantsev, E V

PY - 2016

DA - 2016/08/16

PB - Springer Nature

SP - 2105-2112

IS - 6

VL - 26

PMID - 27530633

SN - 1053-0509

SN - 1573-4994

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2016_Marfin,

author = {Yu S Marfin and M V Shipalova and V O Kurzin and K V Ksenofontova and A. V. Solomonov and E V Rumyantsev},

title = {Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer},

journal = {Journal of Fluorescence},

year = {2016},

volume = {26},

publisher = {Springer Nature},

month = {aug},

url = {https://doi.org/10.1007/s10895-016-1905-1},

number = {6},

pages = {2105--2112},

doi = {10.1007/s10895-016-1905-1}

}

MLA

Cite this

MLA Copy

Marfin, Yu. S., et al. “Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer.” Journal of Fluorescence, vol. 26, no. 6, Aug. 2016, pp. 2105-2112. https://doi.org/10.1007/s10895-016-1905-1.

Publisher

Springer Nature

Journal

Journal of Fluorescence

scimago Q3

wos Q2

SJR

0.422

CiteScore

5.3

Impact factor

3.1

ISSN

10530509 (Print)

15734994 (Electronic)

Profiles

Ksenia V. Ksenofontova