Journal of Fluorescence, том 31, издание 2, номера страниц: 415-425

A New «off-on» Fluorescence Zinc Ion Sensors Based on Iodo- and Bromosubstituted Dipyrromethenes

Тип документаJournal Article
Дата публикации2021-01-07
ИздательSpringer Nature
Название журналаJournal of Fluorescence
Квартиль по SCImagoQ2
Квартиль по Web of ScienceQ3
Импакт-фактор 20212.53
ISSN10530509, 15734994
Clinical Biochemistry
Sociology and Political Science
Social Sciences (miscellaneous)
Clinical Psychology
Краткое описание
Monoiodo- and dibromsubstituted dipyrromethenes HL1 – HL3 were described as a highly sensitive and selective «Off-On» fluorescent chemosensor for Zn2+ based on the chelation-enhanced fluorescence (CHEF) effect. Сoordination reactions of HL1 – HL3 with Zn2+ cations are accompanied by a significant (124 to 215-fold) increase in fluorescence intensity against the background of other metal ions in the binary propanol-1/cyclohexane mixture (1:30). The fluorometric detection limit of Zn2+ ions using HL1 – HL3 sensors is from 3.0∙10−8 to 3.3·10−9 mol/L. The presence of Na+, K+, Ca2+, Mg2+, Mn2+, Ni2+, Co2+, Pb2+ cations does not interfere with the detection of Zn2+. Complexation reactions are accompanied by a visual change in the color of the solution from yellow-orange to pink-raspberry so that the HL1 – HL3 ligands can also be used as a «naked-eye» indicators of the presence of Zn2+ ions.
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1. Nuraneeva E. N., Guseva G. B., Antina E. V. A New «off-on» Fluorescence Zinc Ion Sensors Based on Iodo- and Bromosubstituted Dipyrromethenes // Journal of Fluorescence. 2021. Т. 31. № 2. С. 415–425.


DO - 10.1007/s10895-020-02670-4

UR -

TI - A New «off-on» Fluorescence Zinc Ion Sensors Based on Iodo- and Bromosubstituted Dipyrromethenes

T2 - Journal of Fluorescence

AU - Nuraneeva, Ekaterina N.

AU - Guseva, Galina B.

AU - Antina, Elena V.

PY - 2021

DA - 2021/01/07

PB - Springer Science and Business Media LLC

SP - 415-425

IS - 2

VL - 31

SN - 1053-0509

SN - 1573-4994

ER -

BibTex |


doi = {10.1007/s10895-020-02670-4},

url = {},

year = 2021,

month = {jan},

publisher = {Springer Science and Business Media {LLC}},

volume = {31},

number = {2},

pages = {415--425},

author = {Ekaterina N. Nuraneeva and Galina B. Guseva and Elena V. Antina},

title = {A New {\guillemotleft}off-on{\guillemotright} Fluorescence Zinc Ion Sensors Based on Iodo- and Bromosubstituted Dipyrromethenes},

journal = {Journal of Fluorescence}


Nuraneeva, Ekaterina N., et al. “A New «off-On» Fluorescence Zinc Ion Sensors Based on Iodo- and Bromosubstituted Dipyrromethenes.” Journal of Fluorescence, vol. 31, no. 2, Jan. 2021, pp. 415–25. Crossref,