XPS, UPS, and STM studies of nanostructured CuO films
Тип публикации: Journal Article
Дата публикации: 2008-03-01
scimago Q4
wos Q4
БС3
SJR: 0.211
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00224766, 15738779
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
A Cu1O1.7 oxide film containing a large amout of superstoichiometric oxygen was obtained by low-temperature oxidation of metallic copper in the oxygen plasma. An STM study of the film structure showed that ∼10 nm planar copper oxide nanocrystallites with particles packed parallel to the starting metal surface. In an XPS study, the spectral characteristics of the Cu2p and O1s lines indicated that particles with a CuO lattice formed (E bnd(Cu2p 3/2) = 933.3 eV and a shake-up satellite, E bnd(O1s) = 529.3 eV). The additional superstoichiometric oxygen is localized at the sites of contact of nanoparticles in the interunit space and is characterized by a state with the binding energy E bnd(O1s) = 531.2 eV. Due to the formation of a nanostructure in the films during low-temperature plasma oxidation, the resulting copper oxide has a much lower thermal stability than crystalline oxide CuO.
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Stadnichenko A. I. et al. XPS, UPS, and STM studies of nanostructured CuO films // Journal of Structural Chemistry. 2008. Vol. 49. No. 2. pp. 341-347.
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Stadnichenko A. I., Sorokin A. M., BORONIN A. XPS, UPS, and STM studies of nanostructured CuO films // Journal of Structural Chemistry. 2008. Vol. 49. No. 2. pp. 341-347.
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TY - JOUR
DO - 10.1007/s10947-008-0133-1
UR - https://doi.org/10.1007/s10947-008-0133-1
TI - XPS, UPS, and STM studies of nanostructured CuO films
T2 - Journal of Structural Chemistry
AU - Stadnichenko, A I
AU - Sorokin, A M
AU - BORONIN, A.I.
PY - 2008
DA - 2008/03/01
PB - Pleiades Publishing
SP - 341-347
IS - 2
VL - 49
SN - 0022-4766
SN - 1573-8779
ER -
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@article{2008_Stadnichenko,
author = {A I Stadnichenko and A M Sorokin and A.I. BORONIN},
title = {XPS, UPS, and STM studies of nanostructured CuO films},
journal = {Journal of Structural Chemistry},
year = {2008},
volume = {49},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1007/s10947-008-0133-1},
number = {2},
pages = {341--347},
doi = {10.1007/s10947-008-0133-1}
}
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MLA
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Stadnichenko, A. I., et al. “XPS, UPS, and STM studies of nanostructured CuO films.” Journal of Structural Chemistry, vol. 49, no. 2, Mar. 2008, pp. 341-347. https://doi.org/10.1007/s10947-008-0133-1.