Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism
Тип публикации: Journal Article
Дата публикации: 2018-11-19
SCImago Q2
WOS Q3
БС2
SJR: 0.522
CiteScore: 5.6
Impact factor: 3.5
ISSN: 10229760, 15728935
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Краткое описание
The peculiarities of controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate in the presence of copper-based catalytic system were investigated. It was shown that the polymerization proceeds in a controlled mode in accordance with ARGET ATRP mechanism. The increase of molecular weights in a strict agreement with theoretically predicted values is observed. The formation of copolymers was confirmed by NMR and MALDI TOF MS analysis. The introduction of mentioned monomers to acrylonitrile results in slight decrease of the polymerization rate. The performed calorimetric investigations showed the smoothing of exothermic effect of the oxidative stabilization of formed copolymers.
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ГОСТ
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Grishin I. D. et al. Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism // Journal of Polymer Research. 2018. Vol. 25. No. 12. 261
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Grishin I. D., Stakhi S. A., Kurochkina D. Yu., Grishin D. F. Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism // Journal of Polymer Research. 2018. Vol. 25. No. 12. 261
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TY - JOUR
DO - 10.1007/s10965-018-1653-9
UR - https://doi.org/10.1007/s10965-018-1653-9
TI - Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism
T2 - Journal of Polymer Research
AU - Grishin, I D
AU - Stakhi, S A
AU - Kurochkina, Darya Yu
AU - Grishin, D F
PY - 2018
DA - 2018/11/19
PB - Springer Nature
IS - 12
VL - 25
SN - 1022-9760
SN - 1572-8935
ER -
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@article{2018_Grishin,
author = {I D Grishin and S A Stakhi and Darya Yu Kurochkina and D F Grishin},
title = {Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism},
journal = {Journal of Polymer Research},
year = {2018},
volume = {25},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007/s10965-018-1653-9},
number = {12},
pages = {261},
doi = {10.1007/s10965-018-1653-9}
}
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