volume 25 issue 12 publication number 261

Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism

Publication typeJournal Article
Publication date2018-11-19
scimago Q2
wos Q3
SJR0.505
CiteScore5.1
Impact factor2.8
ISSN10229760, 15728935
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
The peculiarities of controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate in the presence of copper-based catalytic system were investigated. It was shown that the polymerization proceeds in a controlled mode in accordance with ARGET ATRP mechanism. The increase of molecular weights in a strict agreement with theoretically predicted values is observed. The formation of copolymers was confirmed by NMR and MALDI TOF MS analysis. The introduction of mentioned monomers to acrylonitrile results in slight decrease of the polymerization rate. The performed calorimetric investigations showed the smoothing of exothermic effect of the oxidative stabilization of formed copolymers.
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Grishin I. D. et al. Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism // Journal of Polymer Research. 2018. Vol. 25. No. 12. 261
GOST all authors (up to 50) Copy
Grishin I. D., Stakhi S. A., Kurochkina D. Yu., Grishin D. F. Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism // Journal of Polymer Research. 2018. Vol. 25. No. 12. 261
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1007/s10965-018-1653-9
UR - https://doi.org/10.1007/s10965-018-1653-9
TI - Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism
T2 - Journal of Polymer Research
AU - Grishin, I D
AU - Stakhi, S A
AU - Kurochkina, Darya Yu
AU - Grishin, D F
PY - 2018
DA - 2018/11/19
PB - Springer Nature
IS - 12
VL - 25
SN - 1022-9760
SN - 1572-8935
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Grishin,
author = {I D Grishin and S A Stakhi and Darya Yu Kurochkina and D F Grishin},
title = {Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism},
journal = {Journal of Polymer Research},
year = {2018},
volume = {25},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007/s10965-018-1653-9},
number = {12},
pages = {261},
doi = {10.1007/s10965-018-1653-9}
}