Experimental study and kinetic modeling of radical-coordination styrene polymerization with participation of ferrocene
Publication type: Journal Article
Publication date: 2022-09-17
scimago Q2
wos Q3
SJR: 0.505
CiteScore: 5.1
Impact factor: 2.8
ISSN: 10229760, 15728935
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
A kinetic model of styrene polymerization with participation of benzoyl peroxide and ferrocene was developed, based on the radical-coordination mechanism. A peculiarity of this mechanism is a parallel functioning of the radical and coordination channels for the macromolecules formation, during the styrene polymerization. The proposed mechanism of the process is confirmed by calculations on the developed kinetic model. This model allows quantitative description of the experimentally determined (1) dependencies of styrene conversion versus the polymerization time, (2) dependencies of number-average and mass-average molar masses of polystyrene versus the styrene conversion, and (3) dependencies of styrene conversion during its polymerization on a polystyrene macroinitiator versus the polymerization time, the macroinitiator obtained by radical-initiated polymerization with participation of ferrocene. The computational experiments were carried out and analyzed to assess the effect of ferrocene concentration and temperature on the process in question.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
|
|
|
Journal of Polymer Research
1 publication, 16.67%
|
|
|
Industrial & Engineering Chemistry Research
1 publication, 16.67%
|
|
|
Polymer Science - Series D
1 publication, 16.67%
|
|
|
Mendeleev Communications
1 publication, 16.67%
|
|
|
Russian Journal of General Chemistry
1 publication, 16.67%
|
|
|
1
|
Publishers
|
1
2
|
|
|
Pleiades Publishing
2 publications, 33.33%
|
|
|
Research Square Platform LLC
1 publication, 16.67%
|
|
|
Springer Nature
1 publication, 16.67%
|
|
|
American Chemical Society (ACS)
1 publication, 16.67%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 16.67%
|
|
|
1
2
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
6
Total citations:
6
Citations from 2025:
1
(16.67%)
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Tereshchenko K. A. et al. Experimental study and kinetic modeling of radical-coordination styrene polymerization with participation of ferrocene // Journal of Polymer Research. 2022. Vol. 29. No. 10. 429
GOST all authors (up to 50)
Copy
Tereshchenko K. A., Shiyan D. A., Ulitin N. V., Kolesov S. V., Khursan S. L. Experimental study and kinetic modeling of radical-coordination styrene polymerization with participation of ferrocene // Journal of Polymer Research. 2022. Vol. 29. No. 10. 429
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s10965-022-03273-2
UR - https://doi.org/10.1007/s10965-022-03273-2
TI - Experimental study and kinetic modeling of radical-coordination styrene polymerization with participation of ferrocene
T2 - Journal of Polymer Research
AU - Tereshchenko, Konstantin A.
AU - Shiyan, Daria A.
AU - Ulitin, Nikolai V.
AU - Kolesov, Sergei V
AU - Khursan, Sergey L.
PY - 2022
DA - 2022/09/17
PB - Springer Nature
IS - 10
VL - 29
SN - 1022-9760
SN - 1572-8935
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Tereshchenko,
author = {Konstantin A. Tereshchenko and Daria A. Shiyan and Nikolai V. Ulitin and Sergei V Kolesov and Sergey L. Khursan},
title = {Experimental study and kinetic modeling of radical-coordination styrene polymerization with participation of ferrocene},
journal = {Journal of Polymer Research},
year = {2022},
volume = {29},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/s10965-022-03273-2},
number = {10},
pages = {429},
doi = {10.1007/s10965-022-03273-2}
}