Journal of Radioanalytical and Nuclear Chemistry

, том 284 , издание 3 , страницы 641-645

An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K

Тип публикации: Journal Article

Дата публикации: 2010-03-26

Springer Nature

Journal of Radioanalytical and Nuclear Chemistry

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SJR: 0.388

CiteScore: 2.9

Impact factor: 1.6

ISSN: 02365731, 15882780

DOI: 10.1007/s10967-010-0529-1

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Paramagnetic products stabilized in both 4,4′(5′)-di-(tert-butylcyclohexano)-18-crown-6 (DtBuCH18C6) and its solution in 1-octanol upon low temperature (77 K) X-rays irradiation were studied by ESR spectroscopy. Macrocyclic –O–ĊH–CH2– radicals and acyclic O = C(H)–ĊH–O– radicals were found as main radiolysis products in neat DtBuCH18C6. Fraction of acyclic radicals resulting from the macrocycle cleavage was about 50%. No radical products resulted from t-Bu and cyclohexyl fragments were observed. It was concluded that the primary events were essentially concerned with ionization of the polyether moiety. Irradiation of frozen DtBuCH18C6 solutions in 1-octanol resulted in formation of radicals both from crown ether and alcohol.

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Бежин Николай

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37 публикаций, 272 цитирования, 59 рецензий

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Севастопольский государственный университет

Сахалинский государственный университет

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Radiation Physics and Chemistry	Radiation Physics and Chemistry, 2, 40% Radiation Physics and Chemistry 2 публикации, 40%
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Zakurdaeva O. A. et al. An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K // Journal of Radioanalytical and Nuclear Chemistry. 2010. Vol. 284. No. 3. pp. 641-645.

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Zakurdaeva O. A., Nesterov S., Feldman V. I. An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K // Journal of Radioanalytical and Nuclear Chemistry. 2010. Vol. 284. No. 3. pp. 641-645.

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TY - JOUR

DO - 10.1007/s10967-010-0529-1

UR - http://link.springer.com/10.1007/s10967-010-0529-1

TI - An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K

T2 - Journal of Radioanalytical and Nuclear Chemistry

AU - Zakurdaeva, O A

AU - Nesterov, S.V.

AU - Feldman, V I

PY - 2010

DA - 2010/03/26

PB - Springer Nature

SP - 641-645

IS - 3

VL - 284

SN - 0236-5731

SN - 1588-2780

ER -

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@article{2010_Zakurdaeva,

author = {O A Zakurdaeva and S.V. Nesterov and V I Feldman},

title = {An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K},

journal = {Journal of Radioanalytical and Nuclear Chemistry},

year = {2010},

volume = {284},

publisher = {Springer Nature},

month = {mar},

url = {http://link.springer.com/10.1007/s10967-010-0529-1},

number = {3},

pages = {641--645},

doi = {10.1007/s10967-010-0529-1}

}

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Zakurdaeva, O. A., et al. “An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K.” Journal of Radioanalytical and Nuclear Chemistry, vol. 284, no. 3, Mar. 2010, pp. 641-645. http://link.springer.com/10.1007/s10967-010-0529-1.