volume 316 issue 2 pages 535-541

Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride

Publication typeJournal Article
Publication date2018-03-02
scimago Q2
wos Q3
SJR0.388
CiteScore2.9
Impact factor1.6
ISSN02365731, 15882780
Spectroscopy
Analytical Chemistry
Health, Toxicology and Mutagenesis
Public Health, Environmental and Occupational Health
Pollution
Radiology Nuclear Medicine and imaging
Nuclear Energy and Engineering
Abstract
AbstractSmall size benzo-substituted crown ethers are attractive complexing agents for lithium isotope separation by solvent extraction. Low transfer of the crown ethers from solvent to water is a key point for applicability of the extractants. In the present study, 9- and 12-membered crown ethers were synthesized, and their distribution between chloroform and water was studied. Polyether ring size, benzene substituents and addition of LiCl to water were found to effect on distribution constants. Low losses of the macrocycles were observed at single-stage contact with aqueous phase. However, these losses should be taken into account in the design of multistage processes for the preparation of highly enriched lithium isotopes.
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Zakurdaeva O. A. et al. Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride // Journal of Radioanalytical and Nuclear Chemistry. 2018. Vol. 316. No. 2. pp. 535-541.
GOST all authors (up to 50) Copy
Zakurdaeva O. A., Asachenko A. F., Topchiy M. A., Nesterov S. V. Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride // Journal of Radioanalytical and Nuclear Chemistry. 2018. Vol. 316. No. 2. pp. 535-541.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s10967-018-5773-9
UR - http://link.springer.com/10.1007/s10967-018-5773-9
TI - Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Zakurdaeva, Olga A
AU - Asachenko, Andrey F
AU - Topchiy, Maxim A
AU - Nesterov, Sergey V
PY - 2018
DA - 2018/03/02
PB - Springer Nature
SP - 535-541
IS - 2
VL - 316
SN - 0236-5731
SN - 1588-2780
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Zakurdaeva,
author = {Olga A Zakurdaeva and Andrey F Asachenko and Maxim A Topchiy and Sergey V Nesterov},
title = {Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {2018},
volume = {316},
publisher = {Springer Nature},
month = {mar},
url = {http://link.springer.com/10.1007/s10967-018-5773-9},
number = {2},
pages = {535--541},
doi = {10.1007/s10967-018-5773-9}
}
MLA
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MLA Copy
Zakurdaeva, Olga A., et al. “Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride.” Journal of Radioanalytical and Nuclear Chemistry, vol. 316, no. 2, Mar. 2018, pp. 535-541. http://link.springer.com/10.1007/s10967-018-5773-9.