Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride
Тип публикации: Journal Article
Дата публикации: 2018-03-02
scimago Q2
wos Q3
БС2
SJR: 0.388
CiteScore: 2.9
Impact factor: 1.6
ISSN: 02365731, 15882780
Spectroscopy
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AbstractSmall size benzo-substituted crown ethers are attractive complexing agents for lithium isotope separation by solvent extraction. Low transfer of the crown ethers from solvent to water is a key point for applicability of the extractants. In the present study, 9- and 12-membered crown ethers were synthesized, and their distribution between chloroform and water was studied. Polyether ring size, benzene substituents and addition of LiCl to water were found to effect on distribution constants. Low losses of the macrocycles were observed at single-stage contact with aqueous phase. However, these losses should be taken into account in the design of multistage processes for the preparation of highly enriched lithium isotopes.
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Zakurdaeva O. A. et al. Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride // Journal of Radioanalytical and Nuclear Chemistry. 2018. Vol. 316. No. 2. pp. 535-541.
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Zakurdaeva O. A., Asachenko A. F., Topchiy M. A., Nesterov S. V. Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride // Journal of Radioanalytical and Nuclear Chemistry. 2018. Vol. 316. No. 2. pp. 535-541.
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TY - JOUR
DO - 10.1007/s10967-018-5773-9
UR - http://link.springer.com/10.1007/s10967-018-5773-9
TI - Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Zakurdaeva, Olga A
AU - Asachenko, Andrey F
AU - Topchiy, Maxim A
AU - Nesterov, Sergey V
PY - 2018
DA - 2018/03/02
PB - Springer Nature
SP - 535-541
IS - 2
VL - 316
SN - 0236-5731
SN - 1588-2780
ER -
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@article{2018_Zakurdaeva,
author = {Olga A Zakurdaeva and Andrey F Asachenko and Maxim A Topchiy and Sergey V Nesterov},
title = {Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {2018},
volume = {316},
publisher = {Springer Nature},
month = {mar},
url = {http://link.springer.com/10.1007/s10967-018-5773-9},
number = {2},
pages = {535--541},
doi = {10.1007/s10967-018-5773-9}
}
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Zakurdaeva, Olga A., et al. “Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride.” Journal of Radioanalytical and Nuclear Chemistry, vol. 316, no. 2, Mar. 2018, pp. 535-541. http://link.springer.com/10.1007/s10967-018-5773-9.