Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium
A. S. Knyazev
1
,
O V Magaev
2
,
O V Vodyankina
2
,
A I Titkov
3
,
A N Salanov
3
,
S.V Koshcheev
3
,
1
Institute of Petrochemistry, Siberian Division, Russian Academy of Sciences, Tomsk, Russia
|
Publication type: Journal Article
Publication date: 2005-01-01
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The morphology and chemical composition of the surface of silver phosphate are studied. The qualitative and quantitative compositions of silver phosphate are quite the same as those of the surface of the phosphorus-promoted silver catalyst. Silver particles surrounded by silver phosphate form in the subsurface region upon treatment of the sample with hydrogen. As a result, a complex catalytic system is formed in which silver phosphate is both the precursor of the reactive component (metallic silver particles) and the stabilizing matrix for this component. The system obtained is stable toward high temperature and redox reaction media.
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Knyazev A. S. et al. Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium // Kinetics and Catalysis. 2005. Vol. 46. No. 1. pp. 151-156.
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Knyazev A. S., Magaev O. V., Vodyankina O. V., Titkov A. I., Salanov A. N., Koshcheev S., BORONIN A. Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium // Kinetics and Catalysis. 2005. Vol. 46. No. 1. pp. 151-156.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s10975-005-0023-x
UR - https://doi.org/10.1007/s10975-005-0023-x
TI - Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium
T2 - Kinetics and Catalysis
AU - Knyazev, A. S.
AU - Magaev, O V
AU - Vodyankina, O V
AU - Titkov, A I
AU - Salanov, A N
AU - Koshcheev, S.V
AU - BORONIN, A.I.
PY - 2005
DA - 2005/01/01
PB - Pleiades Publishing
SP - 151-156
IS - 1
VL - 46
SN - 0023-1584
SN - 1608-3210
ER -
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BibTex (up to 50 authors)
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@article{2005_Knyazev,
author = {A. S. Knyazev and O V Magaev and O V Vodyankina and A I Titkov and A N Salanov and S.V Koshcheev and A.I. BORONIN},
title = {Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium},
journal = {Kinetics and Catalysis},
year = {2005},
volume = {46},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1007/s10975-005-0023-x},
number = {1},
pages = {151--156},
doi = {10.1007/s10975-005-0023-x}
}
Cite this
MLA
Copy
Knyazev, A. S., et al. “Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium.” Kinetics and Catalysis, vol. 46, no. 1, Jan. 2005, pp. 151-156. https://doi.org/10.1007/s10975-005-0023-x.