Kinetics and Catalysis

, том 46 , издание 1 , страницы 151-156

Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium

Тип публикации: Journal Article

Дата публикации: 2005-01-01

Pleiades Publishing

Kinetics and Catalysis

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wos Q4

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SJR: 0.260

CiteScore: 1.9

Impact factor: 1.4

ISSN: 00231584, 16083210

DOI: 10.1007/s10975-005-0023-x

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General Chemistry

Catalysis

Computer Science Applications

Modeling and Simulation

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The morphology and chemical composition of the surface of silver phosphate are studied. The qualitative and quantitative compositions of silver phosphate are quite the same as those of the surface of the phosphorus-promoted silver catalyst. Silver particles surrounded by silver phosphate form in the subsurface region upon treatment of the sample with hydrogen. As a result, a complex catalytic system is formed in which silver phosphate is both the precursor of the reactive component (metallic silver particles) and the stabilizing matrix for this component. The system obtained is stable toward high temperature and redox reaction media.

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Водянкина Ольга

д.х.н., проф.

143 публикации, 2 224 цитирования, 64 рецензии

Индекс Хирша: 25

Томский Государственный Университет

Области научных интересов

Гетерогенный катализ

Металл-органические координационные полимеры

Механизмы реакций

Селективное жидкофазное окисление

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Knyazev A. S. et al. Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium // Kinetics and Catalysis. 2005. Vol. 46. No. 1. pp. 151-156.

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Knyazev A. S., Magaev O. V., Vodyankina O. V., Titkov A. I., Salanov A. N., Koshcheev S., BORONIN A. Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium // Kinetics and Catalysis. 2005. Vol. 46. No. 1. pp. 151-156.

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TY - JOUR

DO - 10.1007/s10975-005-0023-x

UR - https://doi.org/10.1007/s10975-005-0023-x

TI - Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium

T2 - Kinetics and Catalysis

AU - Knyazev, A. S.

AU - Magaev, O V

AU - Vodyankina, O V

AU - Titkov, A I

AU - Salanov, A N

AU - Koshcheev, S.V

AU - BORONIN, A.I.

PY - 2005

DA - 2005/01/01

PB - Pleiades Publishing

SP - 151-156

IS - 1

VL - 46

SN - 0023-1584

SN - 1608-3210

ER -

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@article{2005_Knyazev,

author = {A. S. Knyazev and O V Magaev and O V Vodyankina and A I Titkov and A N Salanov and S.V Koshcheev and A.I. BORONIN},

title = {Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium},

journal = {Kinetics and Catalysis},

year = {2005},

volume = {46},

publisher = {Pleiades Publishing},

month = {jan},

url = {https://doi.org/10.1007/s10975-005-0023-x},

number = {1},

pages = {151--156},

doi = {10.1007/s10975-005-0023-x}

}

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Knyazev, A. S., et al. “Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of silver phosphate under the action of a reductive medium.” Kinetics and Catalysis, vol. 46, no. 1, Jan. 2005, pp. 151-156. https://doi.org/10.1007/s10975-005-0023-x.