Reductive dehydration of alcohols: A route to alkanes
M V Tsodikov
1
,
V.Ya. Kugel
1
,
F A Yandieva
1
,
G A Kliger
1
,
L S Glebov
1
,
A I Mikaya
1
,
V G Zaikin
1
,
E.V. Slivinskii
1
,
N.A. Plate
1
,
A E Gekhman
2
,
I. I. Moiseev
2
Publication type: Journal Article
Publication date: 2004-11-01
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The reductive dehydration of cyclic (C5, C6) and aliphatic (C2–C4) alcohols into polycycloalkanes and alkanes whose carbon skeleton has at least twice as many atoms as that of the original substrate is reported for the first time. This reaction takes place at 250–350°C and 7–50 atm in the presence of a polymetallic catalytic system based on an iron-containing fused catalyst or a hydrided iron- and titanium-containing intermetallide mixed with a small amount of Pt/Al2O3. The mechanism of this new reaction is discussed in terms of the mechanisms of known reactions of alcohols and aldehydes enlarging the carbon skeleton.
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GOST
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Tsodikov M. V. et al. Reductive dehydration of alcohols: A route to alkanes // Kinetics and Catalysis. 2004. Vol. 45. No. 6. pp. 854-866.
GOST all authors (up to 50)
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Tsodikov M. V., Kugel V., Yandieva F. A., Kliger G. A., Glebov L. S., Mikaya A. I., Zaikin V. G., Slivinskii E., Plate N., Gekhman A. E., Moiseev I. I. Reductive dehydration of alcohols: A route to alkanes // Kinetics and Catalysis. 2004. Vol. 45. No. 6. pp. 854-866.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s10975-005-0050-7
UR - https://doi.org/10.1007/s10975-005-0050-7
TI - Reductive dehydration of alcohols: A route to alkanes
T2 - Kinetics and Catalysis
AU - Tsodikov, M V
AU - Kugel, V.Ya.
AU - Yandieva, F A
AU - Kliger, G A
AU - Glebov, L S
AU - Mikaya, A I
AU - Zaikin, V G
AU - Slivinskii, E.V.
AU - Plate, N.A.
AU - Gekhman, A E
AU - Moiseev, I. I.
PY - 2004
DA - 2004/11/01
PB - Pleiades Publishing
SP - 854-866
IS - 6
VL - 45
SN - 0023-1584
SN - 1608-3210
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2004_Tsodikov,
author = {M V Tsodikov and V.Ya. Kugel and F A Yandieva and G A Kliger and L S Glebov and A I Mikaya and V G Zaikin and E.V. Slivinskii and N.A. Plate and A E Gekhman and I. I. Moiseev},
title = {Reductive dehydration of alcohols: A route to alkanes},
journal = {Kinetics and Catalysis},
year = {2004},
volume = {45},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1007/s10975-005-0050-7},
number = {6},
pages = {854--866},
doi = {10.1007/s10975-005-0050-7}
}
Cite this
MLA
Copy
Tsodikov, M. V., et al. “Reductive dehydration of alcohols: A route to alkanes.” Kinetics and Catalysis, vol. 45, no. 6, Nov. 2004, pp. 854-866. https://doi.org/10.1007/s10975-005-0050-7.
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