Electrochemical mechanism of silver nanoprisms transformation in aqueous solutions containing the halide ions
Publication type: Journal Article
Publication date: 2018-02-01
scimago Q2
wos Q2
SJR: 0.469
CiteScore: 4.0
Impact factor: 2.6
ISSN: 13880764, 1572896X
General Chemistry
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
General Materials Science
Bioengineering
Modeling and Simulation
Abstract
The transformation process of 20–50 nm silver nanoprisms in the presence of Cl-, Br-, and I- ions was studied. The threshold concentrations of halide ions that initiate the transformation do not depend on the size of nanoprisms. It was shown that the structure change is caused by the formation of poorly soluble silver complexes on nanoprisms and occurs by an electrochemical mechanism. The induction period preceding the onset of shape transformation is related to the formation of silver halide nanoelectrodes. The electrochemical reactions involving silver and silver halide nanoelectrodes induce restructuring of silver particles the efficiency of which is determined by electrode potentials.
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Abkhalimov E. V., Timofeev A. A., Ershov B. G. Electrochemical mechanism of silver nanoprisms transformation in aqueous solutions containing the halide ions // Journal of Nanoparticle Research. 2018. Vol. 20. No. 2. 26
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Abkhalimov E. V., Timofeev A. A., Ershov B. G. Electrochemical mechanism of silver nanoprisms transformation in aqueous solutions containing the halide ions // Journal of Nanoparticle Research. 2018. Vol. 20. No. 2. 26
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TY - JOUR
DO - 10.1007/s11051-018-4133-6
UR - https://doi.org/10.1007/s11051-018-4133-6
TI - Electrochemical mechanism of silver nanoprisms transformation in aqueous solutions containing the halide ions
T2 - Journal of Nanoparticle Research
AU - Abkhalimov, E V
AU - Timofeev, A. A.
AU - Ershov, B G
PY - 2018
DA - 2018/02/01
PB - Springer Nature
IS - 2
VL - 20
SN - 1388-0764
SN - 1572-896X
ER -
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@article{2018_Abkhalimov,
author = {E V Abkhalimov and A. A. Timofeev and B G Ershov},
title = {Electrochemical mechanism of silver nanoprisms transformation in aqueous solutions containing the halide ions},
journal = {Journal of Nanoparticle Research},
year = {2018},
volume = {20},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007/s11051-018-4133-6},
number = {2},
pages = {26},
doi = {10.1007/s11051-018-4133-6}
}
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