Transition from Internal to External Oxidation in Binary Fe–Cr Alloys Around 900 °C
Publication type: Journal Article
Publication date: 2024-12-06
scimago Q2
wos Q2
SJR: 0.289
CiteScore: 3.2
Impact factor: 2.0
ISSN: 27318397, 27318400
Abstract
The transition from external to internal oxidation of a binary Fe-10Cr alloy has been investigated in Fe/FeO Rhines pack (RP) and H2/H2O between 850 and 900 °C. Internal oxidation is facilitated by increasing temperature and presence of water vapor. A classical Wagnerian diffusion analysis predicts external oxidation for ferritic (BCC) Fe-10Cr and internal oxidation for austenitic (FCC) Fe-10Cr. The α-to-γ transformation is demonstrated to be the primary factor promoting internal oxidation in Fe–Cr around 900 °C. Water vapor is believed to promote internal oxidation due to a higher reactivity of H2O compared to O2 and higher preferential adsorption of the H2O molecule.
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Chyrkin A. et al. Transition from Internal to External Oxidation in Binary Fe–Cr Alloys Around 900 °C // High Temperature Corrosion of Materials. 2024. Vol. 102. No. 1. pp. 1-22.
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Chyrkin A., Froitzheim J., Quadakkers W. J. Transition from Internal to External Oxidation in Binary Fe–Cr Alloys Around 900 °C // High Temperature Corrosion of Materials. 2024. Vol. 102. No. 1. pp. 1-22.
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TY - JOUR
DO - 10.1007/s11085-024-10322-2
UR - https://link.springer.com/10.1007/s11085-024-10322-2
TI - Transition from Internal to External Oxidation in Binary Fe–Cr Alloys Around 900 °C
T2 - High Temperature Corrosion of Materials
AU - Chyrkin, A
AU - Froitzheim, J.
AU - Quadakkers, W. J.
PY - 2024
DA - 2024/12/06
PB - Springer Nature
SP - 1-22
IS - 1
VL - 102
SN - 2731-8397
SN - 2731-8400
ER -
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@article{2024_Chyrkin,
author = {A Chyrkin and J. Froitzheim and W. J. Quadakkers},
title = {Transition from Internal to External Oxidation in Binary Fe–Cr Alloys Around 900 °C},
journal = {High Temperature Corrosion of Materials},
year = {2024},
volume = {102},
publisher = {Springer Nature},
month = {dec},
url = {https://link.springer.com/10.1007/s11085-024-10322-2},
number = {1},
pages = {1--22},
doi = {10.1007/s11085-024-10322-2}
}
Cite this
MLA
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Chyrkin, A., et al. “Transition from Internal to External Oxidation in Binary Fe–Cr Alloys Around 900 °C.” High Temperature Corrosion of Materials, vol. 102, no. 1, Dec. 2024, pp. 1-22. https://link.springer.com/10.1007/s11085-024-10322-2.