An XPS study of interaction of neptunyl(V) in aqueous solution with goethite (α-FeOOH)
Yu.A. Teterin
1
,
S N Kalmykov
2
,
A. P. Novikov
3
,
L Dj Vukcevic
4
,
A.Yu. Teterin
1
,
K I Maslakov
1
,
I.O Utkin
1
,
A B Khasanova
2
,
N S Shcherbina
2
4
Podgorica University, Podgorica, Serbia and Montenegro
|
Publication type: Journal Article
Publication date: 2004-11-01
scimago Q3
wos Q4
SJR: 0.285
CiteScore: 1.6
Impact factor: 1.0
ISSN: 10663622, 16083288
Physical and Theoretical Chemistry
Abstract
Sorption and physicochemical state of Np on the goethite (α-FeOOH) surface were studied. The oxidation state of Np on the α-FeOOH surface was studied by the liquid extraction. The neptunium complexes formed on the surface were studied by X-ray photoelectron spectroscopy. The ionic and elemental composition of the goethite surface and NpO 2 + complexes with α-FeOOH were determined from the XPS data. No Np(IV) and Np(VI) compounds were detected. Neptunyl(V) Np(V)O 2 + forms complexes with the surface groups of α-FeOOH. The equatorial plane of these complexes is occupied by the oxygen atoms of α-FeOOH and water and/or carbonate group CO 3 2− .
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Teterin Y. et al. An XPS study of interaction of neptunyl(V) in aqueous solution with goethite (α-FeOOH) // Radiochemistry. 2004. Vol. 46. No. 6. pp. 545-551.
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Teterin Y., Kalmykov S. N., Novikov A. P., Sapozhnikov Y., Vukcevic L. D., Teterin A., Maslakov K. I., Utkin I., Khasanova A. B., Shcherbina N. S. An XPS study of interaction of neptunyl(V) in aqueous solution with goethite (α-FeOOH) // Radiochemistry. 2004. Vol. 46. No. 6. pp. 545-551.
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TY - JOUR
DO - 10.1007/s11137-005-0024-7
UR - http://link.springer.com/10.1007/s11137-005-0024-7
TI - An XPS study of interaction of neptunyl(V) in aqueous solution with goethite (α-FeOOH)
T2 - Radiochemistry
AU - Teterin, Yu.A.
AU - Kalmykov, S N
AU - Novikov, A. P.
AU - Sapozhnikov, Yu.A.
AU - Vukcevic, L Dj
AU - Teterin, A.Yu.
AU - Maslakov, K I
AU - Utkin, I.O
AU - Khasanova, A B
AU - Shcherbina, N S
PY - 2004
DA - 2004/11/01
PB - Springer Nature
SP - 545-551
IS - 6
VL - 46
SN - 1066-3622
SN - 1608-3288
ER -
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BibTex (up to 50 authors)
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@article{2004_Teterin,
author = {Yu.A. Teterin and S N Kalmykov and A. P. Novikov and Yu.A. Sapozhnikov and L Dj Vukcevic and A.Yu. Teterin and K I Maslakov and I.O Utkin and A B Khasanova and N S Shcherbina},
title = {An XPS study of interaction of neptunyl(V) in aqueous solution with goethite (α-FeOOH)},
journal = {Radiochemistry},
year = {2004},
volume = {46},
publisher = {Springer Nature},
month = {nov},
url = {http://link.springer.com/10.1007/s11137-005-0024-7},
number = {6},
pages = {545--551},
doi = {10.1007/s11137-005-0024-7}
}
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MLA
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Teterin, Yu.A., et al. “An XPS study of interaction of neptunyl(V) in aqueous solution with goethite (α-FeOOH).” Radiochemistry, vol. 46, no. 6, Nov. 2004, pp. 545-551. http://link.springer.com/10.1007/s11137-005-0024-7.