Selective synthesis of ethylbenzene by alkylation of benzene with diethyl carbonate over MCM-22 modified by MgO

Bing Xue 1, 2
, 
Yongxin Li 2
, 
Wang Shujun 1
, 
Hongyan Liu 1
, 
Chongfu Xu 2
1
 
2
 
Department of Chemical Engineering, Jiangsu Polytechnic University, Changzhou, China | 
Тип публикации: Journal Article
Дата публикации: 2010-05-19
Springer Nature
scimago Q3
wos Q4
БС3
SJR: 0.363
CiteScore: 3.3
Impact factor: 1.7
ISSN: 18785190, 18785204
Catalysis
Physical and Theoretical Chemistry
Краткое описание
Selective synthesis of ethylbenzene by vapor phase alkylation of benzene with diethyl carbonate was carried out over MCM-22 modified by MgO. Characterization results show that the number of Brønsted acid sites on MCM-22 decreased significantly after MgO modification, which resulted in a decrease in activity. The selectivity for ethylbenzene was improved greatly over MCM-22 modified by MgO, which can be attributed to the effective suppression of subsequent alkylation of ethylbenzene by the reduction in Brønsted acid sites.
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Xue B. et al. Selective synthesis of ethylbenzene by alkylation of benzene with diethyl carbonate over MCM-22 modified by MgO // Reaction Kinetics, Mechanisms and Catalysis. 2010.
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Xue B., Li Y., Shujun W., Liu H., Xu C. Selective synthesis of ethylbenzene by alkylation of benzene with diethyl carbonate over MCM-22 modified by MgO // Reaction Kinetics, Mechanisms and Catalysis. 2010.
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TY - JOUR
DO - 10.1007/s11144-010-0198-7
UR - https://doi.org/10.1007/s11144-010-0198-7
TI - Selective synthesis of ethylbenzene by alkylation of benzene with diethyl carbonate over MCM-22 modified by MgO
T2 - Reaction Kinetics, Mechanisms and Catalysis
AU - Xue, Bing
AU - Li, Yongxin
AU - Shujun, Wang
AU - Liu, Hongyan
AU - Xu, Chongfu
PY - 2010
DA - 2010/05/19
PB - Springer Nature
SN - 1878-5190
SN - 1878-5204
ER -
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@article{2010_Xue,
author = {Bing Xue and Yongxin Li and Wang Shujun and Hongyan Liu and Chongfu Xu},
title = {Selective synthesis of ethylbenzene by alkylation of benzene with diethyl carbonate over MCM-22 modified by MgO},
journal = {Reaction Kinetics, Mechanisms and Catalysis},
year = {2010},
publisher = {Springer Nature},
month = {may},
url = {https://doi.org/10.1007/s11144-010-0198-7},
doi = {10.1007/s11144-010-0198-7}
}