Reaction Kinetics, Mechanisms and Catalysis

, том 117 , издание 2 , страницы 405-415

Kinetic features of chain initiation reactions during the oxidation of unsaturated compounds in media of different polarity

Тип публикации: Journal Article

Дата публикации: 2015-11-27

Springer Nature

Reaction Kinetics, Mechanisms and Catalysis

scimago Q3

wos Q4

БС3

SJR: 0.363

CiteScore: 3.3

Impact factor: 1.7

ISSN: 18785190, 18785204

DOI: 10.1007/s11144-015-0957-6

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Catalysis

Physical and Theoretical Chemistry

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The kinetics of chain initiation during the auto-oxidation of some unsaturated compounds (methyl linoleate, allyl acetate, allyl propyl ether, styrene, α-methyl styrene, butyl acrylate, butyl methacrylate, ethyl cinnamate, trans-1,2-diphenylethylene, trans,trans-1,4-diphenylbutadiene-1,3) in solvents of different polarity was studied at temperatures 343–383 K. The data array comprised of chain initiation rate constants of bi- and trimolecular reactions was obtained. It was shown that in some cases, the polarity of the medium is the key factor defining the initiation mechanism.

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Sirick A. et al. Kinetic features of chain initiation reactions during the oxidation of unsaturated compounds in media of different polarity // Reaction Kinetics, Mechanisms and Catalysis. 2015. Vol. 117. No. 2. pp. 405-415.

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Sirick A., Lednev S., Moskalenko I., Machtin V., Pliss E. Kinetic features of chain initiation reactions during the oxidation of unsaturated compounds in media of different polarity // Reaction Kinetics, Mechanisms and Catalysis. 2015. Vol. 117. No. 2. pp. 405-415.

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TY - JOUR

DO - 10.1007/s11144-015-0957-6

UR - https://doi.org/10.1007/s11144-015-0957-6

TI - Kinetic features of chain initiation reactions during the oxidation of unsaturated compounds in media of different polarity

T2 - Reaction Kinetics, Mechanisms and Catalysis

AU - Sirick, Andrew

AU - Lednev, Sergey

AU - Moskalenko, Ivan

AU - Machtin, Vyacheslav

AU - Pliss, Eugene

PY - 2015

DA - 2015/11/27

PB - Springer Nature

SP - 405-415

IS - 2

VL - 117

SN - 1878-5190

SN - 1878-5204

ER -

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@article{2015_Sirick,

author = {Andrew Sirick and Sergey Lednev and Ivan Moskalenko and Vyacheslav Machtin and Eugene Pliss},

title = {Kinetic features of chain initiation reactions during the oxidation of unsaturated compounds in media of different polarity},

journal = {Reaction Kinetics, Mechanisms and Catalysis},

year = {2015},

volume = {117},

publisher = {Springer Nature},

month = {nov},

url = {https://doi.org/10.1007/s11144-015-0957-6},

number = {2},

pages = {405--415},

doi = {10.1007/s11144-015-0957-6}

}

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Sirick, Andrew, et al. “Kinetic features of chain initiation reactions during the oxidation of unsaturated compounds in media of different polarity.” Reaction Kinetics, Mechanisms and Catalysis, vol. 117, no. 2, Nov. 2015, pp. 405-415. https://doi.org/10.1007/s11144-015-0957-6.