Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins
Publication type: Journal Article
Publication date: 2015-06-29
scimago Q2
wos Q2
SJR: 0.528
CiteScore: 5.7
Impact factor: 3.5
ISSN: 09226168, 15685675
General Chemistry
Abstract
The electrolysis of pyrazoline-5-ones and activated olefins in the presence of sodium bromide as mediator in alcohols in an undivided cell results in efficient formation of the substituted spirocyclopropylpyrazolones in 50–85 % yields. This novel electrocatalytic process opens a convenient way to functionalized spirocyclopropylpyrazolones—the promising compounds for the different biomedical applications. Thus, the simple electrocatalytic system can produce in an undivided cell under mild conditions the electrochemically induced cascade reaction of pyrazoline-5-ones with activated olefins.
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GOST
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Elinson M. N. et al. Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins // Research on Chemical Intermediates. 2015. Vol. 42. No. 3. pp. 2191-2200.
GOST all authors (up to 50)
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Elinson M. N., Dorofeeva E. O., Vereshchagin A. N., Korshunov A. D., Egorov M. P. Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins // Research on Chemical Intermediates. 2015. Vol. 42. No. 3. pp. 2191-2200.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s11164-015-2142-y
UR - https://doi.org/10.1007/s11164-015-2142-y
TI - Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins
T2 - Research on Chemical Intermediates
AU - Elinson, Michail N
AU - Dorofeeva, Evgeniya O
AU - Vereshchagin, Anatoly N.
AU - Korshunov, Alexander D
AU - Egorov, Mikhail P.
PY - 2015
DA - 2015/06/29
PB - Springer Nature
SP - 2191-2200
IS - 3
VL - 42
SN - 0922-6168
SN - 1568-5675
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Elinson,
author = {Michail N Elinson and Evgeniya O Dorofeeva and Anatoly N. Vereshchagin and Alexander D Korshunov and Mikhail P. Egorov},
title = {Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins},
journal = {Research on Chemical Intermediates},
year = {2015},
volume = {42},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s11164-015-2142-y},
number = {3},
pages = {2191--2200},
doi = {10.1007/s11164-015-2142-y}
}
Cite this
MLA
Copy
Elinson, Michail N., et al. “Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins.” Research on Chemical Intermediates, vol. 42, no. 3, Jun. 2015, pp. 2191-2200. https://doi.org/10.1007/s11164-015-2142-y.
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