Research on Chemical Intermediates

, том 42 , издание 3 , страницы 2191-2200

Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins

Тип публикации: Journal Article

Дата публикации: 2015-06-29

Springer Nature

Research on Chemical Intermediates

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WOS Q2

БС2

SJR: 0.455

CiteScore: 5.6

Impact factor: 3.3

ISSN: 09226168, 15685675

DOI: 10.1007/s11164-015-2142-y

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General Chemistry

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The electrolysis of pyrazoline-5-ones and activated olefins in the presence of sodium bromide as mediator in alcohols in an undivided cell results in efficient formation of the substituted spirocyclopropylpyrazolones in 50–85 % yields. This novel electrocatalytic process opens a convenient way to functionalized spirocyclopropylpyrazolones—the promising compounds for the different biomedical applications. Thus, the simple electrocatalytic system can produce in an undivided cell under mild conditions the electrochemically induced cascade reaction of pyrazoline-5-ones with activated olefins.

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Elinson M. N. et al. Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins // Research on Chemical Intermediates. 2015. Vol. 42. No. 3. pp. 2191-2200.

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Elinson M. N., Dorofeeva E. O., Vereshchagin A. N., Korshunov A. D., Egorov M. P. Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins // Research on Chemical Intermediates. 2015. Vol. 42. No. 3. pp. 2191-2200.

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TY - JOUR

DO - 10.1007/s11164-015-2142-y

UR - https://doi.org/10.1007/s11164-015-2142-y

TI - Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins

T2 - Research on Chemical Intermediates

AU - Elinson, Michail N

AU - Dorofeeva, Evgeniya O

AU - Vereshchagin, Anatoly N.

AU - Korshunov, Alexander D

AU - Egorov, Mikhail P.

PY - 2015

DA - 2015/06/29

PB - Springer Nature

SP - 2191-2200

IS - 3

VL - 42

SN - 0922-6168

SN - 1568-5675

ER -

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@article{2015_Elinson,

author = {Michail N Elinson and Evgeniya O Dorofeeva and Anatoly N. Vereshchagin and Alexander D Korshunov and Mikhail P. Egorov},

title = {Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins},

journal = {Research on Chemical Intermediates},

year = {2015},

volume = {42},

publisher = {Springer Nature},

month = {jun},

url = {https://doi.org/10.1007/s11164-015-2142-y},

number = {3},

pages = {2191--2200},

doi = {10.1007/s11164-015-2142-y}

}

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MLA Скопировать

Elinson, Michail N., et al. “Simple and facile electrocatalytic approach to medicinally relevant spirocyclopropylpyrazolones directly from pyrazoline-5-ones and activated olefins.” Research on Chemical Intermediates, vol. 42, no. 3, Jun. 2015, pp. 2191-2200. https://doi.org/10.1007/s11164-015-2142-y.

Издатель

Springer Nature

Журнал

Research on Chemical Intermediates

SCImago Q2

WOS Q2

БС2

SJR

0.455

CiteScore

5.6

Impact factor