Synthesis and reactivity of metal-containing monomers. Part 59. Preparation and polymerization transformations of vinyl and isopropenyl derivatives of hafnocene dichloride
Publication type: Journal Article
Publication date: 2005-01-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Novel vinyl- and isopropenyl-substituted cyclopentadienyl complexes of hafnium(IV), [C5H4(CR=CH2)]2HfCl2[R = H (5), CH3 (6)], were prepared and characterized. The organometallic monomers obtained were shown to undergo radical or anionic homopolymerization. Copolymerization of these metallocenes with styrene was performed. The potential applications of the metal polymers in question were considered.
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Krutko D. P. et al. Synthesis and reactivity of metal-containing monomers. Part 59. Preparation and polymerization transformations of vinyl and isopropenyl derivatives of hafnocene dichloride // Russian Chemical Bulletin. 2005. Vol. 54. No. 1. pp. 247-251.
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Krutko D. P., Borzov M. V., Lemenovskii D. A., Dzhardimalieva G., Pomogailo A. Synthesis and reactivity of metal-containing monomers. Part 59. Preparation and polymerization transformations of vinyl and isopropenyl derivatives of hafnocene dichloride // Russian Chemical Bulletin. 2005. Vol. 54. No. 1. pp. 247-251.
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TY - JOUR
DO - 10.1007/s11172-005-0244-1
UR - http://link.springer.com/10.1007/s11172-005-0244-1
TI - Synthesis and reactivity of metal-containing monomers. Part 59. Preparation and polymerization transformations of vinyl and isopropenyl derivatives of hafnocene dichloride
T2 - Russian Chemical Bulletin
AU - Krutko, D P
AU - Borzov, M V
AU - Lemenovskii, D A
AU - Dzhardimalieva, G.I.
AU - Pomogailo, A.D.
PY - 2005
DA - 2005/01/01
PB - Springer Nature
SP - 247-251
IS - 1
VL - 54
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2005_Krutko,
author = {D P Krutko and M V Borzov and D A Lemenovskii and G.I. Dzhardimalieva and A.D. Pomogailo},
title = {Synthesis and reactivity of metal-containing monomers. Part 59. Preparation and polymerization transformations of vinyl and isopropenyl derivatives of hafnocene dichloride},
journal = {Russian Chemical Bulletin},
year = {2005},
volume = {54},
publisher = {Springer Nature},
month = {jan},
url = {http://link.springer.com/10.1007/s11172-005-0244-1},
number = {1},
pages = {247--251},
doi = {10.1007/s11172-005-0244-1}
}
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Krutko, D. P., et al. “Synthesis and reactivity of metal-containing monomers. Part 59. Preparation and polymerization transformations of vinyl and isopropenyl derivatives of hafnocene dichloride.” Russian Chemical Bulletin, vol. 54, no. 1, Jan. 2005, pp. 247-251. http://link.springer.com/10.1007/s11172-005-0244-1.