Regioselectivity of reactions of vinyl- and isopropenylcyclopentadienide anions with electrophilic agents. Synthesis and crystal structures of complexes [C5 H4 C(Me)=CH2 ]ZrCl3 ·2THF and [C5 Me4 CH=CH2 ]ZrCl3 ·2THF
Publication type: Journal Article
Publication date: 2005-02-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Regioselectivity of the reactions of lithium vinyl- and isopropenylcyclopentadienides C5H4C(R)=CH2 -Li+(R = H, Me) and lithium tetramethylvinylcyclopentadienide C5Me4CH=CH2 -Li+ with various electrophilic agents (Me3SiCl, Me3SnCl, Et2PCl, 2-chloro-1, 3-dioxaphospholane, and MeI) was studied. Two new monocyclopentadienyl zirconium complexes, [C5H4C(Me) = CH2]ZrCl3 · 2THF and [C5Me4CH=CH2]ZrCl3 · 2THF, were synthesized. Their crystal structures were established by X-ray diffraction. The results of quantum chemical calculations for the C5H4C(R) = CH2 - (R = H, Me) and C5Me4CH=CH2 - anions by the DFT method (RMPW1PW91) with the 6-311+G(d, p) split valence basis set are in good agreement with experimental data on the regioselectivity of their reactions with electrophilic agents.
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Krutko D. P. et al. Regioselectivity of reactions of vinyl- and isopropenylcyclopentadienide anions with electrophilic agents. Synthesis and crystal structures of complexes [C5H4C(Me)=CH2]ZrCl3·2THF and [C5Me4CH=CH2]ZrCl3·2THF // Russian Chemical Bulletin. 2005. Vol. 54. No. 2. pp. 390-399.
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Krutko D. P., Borzov M. V., Dolomanov O. V., Churakov A., Lemenovskii D. A. Regioselectivity of reactions of vinyl- and isopropenylcyclopentadienide anions with electrophilic agents. Synthesis and crystal structures of complexes [C5H4C(Me)=CH2]ZrCl3·2THF and [C5Me4CH=CH2]ZrCl3·2THF // Russian Chemical Bulletin. 2005. Vol. 54. No. 2. pp. 390-399.
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TY - JOUR
DO - 10.1007/s11172-005-0263-y
UR - http://link.springer.com/10.1007/s11172-005-0263-y
TI - Regioselectivity of reactions of vinyl- and isopropenylcyclopentadienide anions with electrophilic agents. Synthesis and crystal structures of complexes [C5H4C(Me)=CH2]ZrCl3·2THF and [C5Me4CH=CH2]ZrCl3·2THF
T2 - Russian Chemical Bulletin
AU - Krutko, D P
AU - Borzov, M V
AU - Dolomanov, O V
AU - Churakov, A.V.
AU - Lemenovskii, D A
PY - 2005
DA - 2005/02/01
PB - Springer Nature
SP - 390-399
IS - 2
VL - 54
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2005_Krutko,
author = {D P Krutko and M V Borzov and O V Dolomanov and A.V. Churakov and D A Lemenovskii},
title = {Regioselectivity of reactions of vinyl- and isopropenylcyclopentadienide anions with electrophilic agents. Synthesis and crystal structures of complexes [C5H4C(Me)=CH2]ZrCl3·2THF and [C5Me4CH=CH2]ZrCl3·2THF},
journal = {Russian Chemical Bulletin},
year = {2005},
volume = {54},
publisher = {Springer Nature},
month = {feb},
url = {http://link.springer.com/10.1007/s11172-005-0263-y},
number = {2},
pages = {390--399},
doi = {10.1007/s11172-005-0263-y}
}
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MLA
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Krutko, D. P., et al. “Regioselectivity of reactions of vinyl- and isopropenylcyclopentadienide anions with electrophilic agents. Synthesis and crystal structures of complexes [C5H4C(Me)=CH2]ZrCl3·2THF and [C5Me4CH=CH2]ZrCl3·2THF.” Russian Chemical Bulletin, vol. 54, no. 2, Feb. 2005, pp. 390-399. http://link.springer.com/10.1007/s11172-005-0263-y.