Unusual case of catalysis by palladium clusters
I P Stolarov
1
,
Zh V Dobrokhotova
1
,
G. N. Kryukova
2
,
N.Yu. Kozitsyna
1
,
A E Gekhman
1
,
M.N. Vargaftik
1
,
I. I. Moiseev
1
Publication type: Journal Article
Publication date: 2005-03-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
An unusual for Pd catalysts dehydration of α-alkyl and α, α′-dialkylbenzyl alcohols PhCR′R″OH (R′ = H, Me, Et, Bu; R″ = H, Me) occurs in the presence of the palladium(I) cluster [Pd4(CO)4(OAc)4] (1) in an inert atmosphere to form ethers PhCR′R″-O-CR′ R″ and water. The catalyst is an intermediate of cluster 1 reduction to Pd black, while neither the starting cluster 1, nor Pd black, which is the decomposition product, are active in the catalysis of this reaction.
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Stolarov I. P. et al. Unusual case of catalysis by palladium clusters // Russian Chemical Bulletin. 2005. Vol. 54. No. 3. pp. 803-806.
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Stolarov I. P., Dobrokhotova Z. V., Kryukova G. N., Kozitsyna N., Gekhman A. E., Vargaftik M., Moiseev I. I. Unusual case of catalysis by palladium clusters // Russian Chemical Bulletin. 2005. Vol. 54. No. 3. pp. 803-806.
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RIS
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TY - JOUR
DO - 10.1007/s11172-005-0324-2
UR - http://link.springer.com/10.1007/s11172-005-0324-2
TI - Unusual case of catalysis by palladium clusters
T2 - Russian Chemical Bulletin
AU - Stolarov, I P
AU - Dobrokhotova, Zh V
AU - Kryukova, G. N.
AU - Kozitsyna, N.Yu.
AU - Gekhman, A E
AU - Vargaftik, M.N.
AU - Moiseev, I. I.
PY - 2005
DA - 2005/03/01
PB - Springer Nature
SP - 803-806
IS - 3
VL - 54
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2005_Stolarov,
author = {I P Stolarov and Zh V Dobrokhotova and G. N. Kryukova and N.Yu. Kozitsyna and A E Gekhman and M.N. Vargaftik and I. I. Moiseev},
title = {Unusual case of catalysis by palladium clusters},
journal = {Russian Chemical Bulletin},
year = {2005},
volume = {54},
publisher = {Springer Nature},
month = {mar},
url = {http://link.springer.com/10.1007/s11172-005-0324-2},
number = {3},
pages = {803--806},
doi = {10.1007/s11172-005-0324-2}
}
Cite this
MLA
Copy
Stolarov, I. P., et al. “Unusual case of catalysis by palladium clusters.” Russian Chemical Bulletin, vol. 54, no. 3, Mar. 2005, pp. 803-806. http://link.springer.com/10.1007/s11172-005-0324-2.