Russian Chemical Bulletin

, том 54 , издание 6 , страницы 1458-1466

Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals

V I Feldman ^{1, 2, 3}

F F Sukhov ¹

A. Yu. Orlov ²

I V Tyulpina ¹

E A Logacheva ^{2, 3}

D A Tyurin ³

Скрыть аффилиации авторов Показать аффилиации авторов: 3 аффилиации

L. Ya. Karpov Institute of Physical Chemistry, Moscow, Russian Federation |

N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation |

Department of Chemistry, M. V. Lomonosov Moscow State University, Moscow, Russian Federation |

Тип публикации: Journal Article

Дата публикации: 2005-06-01

Springer Nature

Russian Chemical Bulletin

scimago Q3

БС2

SJR: 0.305

CiteScore: 2.8

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ISSN: 10665285, 15739171

DOI: 10.1007/s11172-005-0427-9

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General Chemistry

Краткое описание

The formation of HXeCCH molecules and HXeCC⋅ radicals resulting from chemical reactions in solid xenon-acetylene systems irradiated with fast electrons was studied by low-temperature IR and EPR spectroscopies. The data obtained confirm the assignment of an absorption band with maximum at 1478 cm−1 to the H-Xe stretching vibrations in the HXeCC⋅ radical. Relativistic density functional calculations with inclusion of anharmonic corrections permit a quantitative description of the vibrational spectra of xenon-containing molecules and radicals. Preliminary experimental and computational data on the magnetic resonance parameters of the HXeCC⋅ radical were obtained. This radical is characterized by large hyperfine coupling constants with magnetic nuclei of the xenon isotopes.

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Московский государственный университет имени М.В. Ломоносова

Области научных интересов

Ab initio

Matrix isolation

Астрофизика

Взаимодействие рентгеновского и синхротронного излучений с веществом

Высокопроизводительные вычисления

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Невалентные взаимодействия

Нековалентные взаимодействия

Расчетные методы в химии

Рентгеновское излучение

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Акимов Александр

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Федеральный исследовательский центр проблем химической физики и медицинской химии РАН

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Feldman V. I. et al. Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals // Russian Chemical Bulletin. 2005. Vol. 54. No. 6. pp. 1458-1466.

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Feldman V. I., Sukhov F. F., Orlov A. Y., Tyulpina I. V., Logacheva E. A., Tyurin D. A. Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals // Russian Chemical Bulletin. 2005. Vol. 54. No. 6. pp. 1458-1466.

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TY - JOUR

DO - 10.1007/s11172-005-0427-9

UR - http://link.springer.com/10.1007/s11172-005-0427-9

TI - Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals

T2 - Russian Chemical Bulletin

AU - Feldman, V I

AU - Sukhov, F F

AU - Orlov, A. Yu.

AU - Tyulpina, I V

AU - Logacheva, E A

AU - Tyurin, D A

PY - 2005

DA - 2005/06/01

PB - Springer Nature

SP - 1458-1466

IS - 6

VL - 54

SN - 1066-5285

SN - 1573-9171

ER -

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@article{2005_Feldman,

author = {V I Feldman and F F Sukhov and A. Yu. Orlov and I V Tyulpina and E A Logacheva and D A Tyurin},

title = {Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals},

journal = {Russian Chemical Bulletin},

year = {2005},

volume = {54},

publisher = {Springer Nature},

month = {jun},

url = {http://link.springer.com/10.1007/s11172-005-0427-9},

number = {6},

pages = {1458--1466},

doi = {10.1007/s11172-005-0427-9}

}

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Feldman, V. I., et al. “Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals.” Russian Chemical Bulletin, vol. 54, no. 6, Jun. 2005, pp. 1458-1466. http://link.springer.com/10.1007/s11172-005-0427-9.