Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals
Publication type: Journal Article
Publication date: 2005-06-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The formation of HXeCCH molecules and HXeCC⋅ radicals resulting from chemical reactions in solid xenon-acetylene systems irradiated with fast electrons was studied by low-temperature IR and EPR spectroscopies. The data obtained confirm the assignment of an absorption band with maximum at 1478 cm−1 to the H-Xe stretching vibrations in the HXeCC⋅ radical. Relativistic density functional calculations with inclusion of anharmonic corrections permit a quantitative description of the vibrational spectra of xenon-containing molecules and radicals. Preliminary experimental and computational data on the magnetic resonance parameters of the HXeCC⋅ radical were obtained. This radical is characterized by large hyperfine coupling constants with magnetic nuclei of the xenon isotopes.
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Feldman V. I. et al. Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals // Russian Chemical Bulletin. 2005. Vol. 54. No. 6. pp. 1458-1466.
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Feldman V. I., Sukhov F. F., Orlov A. Y., Tyulpina I. V., Logacheva E. A., Tyurin D. A. Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals // Russian Chemical Bulletin. 2005. Vol. 54. No. 6. pp. 1458-1466.
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RIS
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TY - JOUR
DO - 10.1007/s11172-005-0427-9
UR - http://link.springer.com/10.1007/s11172-005-0427-9
TI - Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals
T2 - Russian Chemical Bulletin
AU - Feldman, V I
AU - Sukhov, F F
AU - Orlov, A. Yu.
AU - Tyulpina, I V
AU - Logacheva, E A
AU - Tyurin, D A
PY - 2005
DA - 2005/06/01
PB - Springer Nature
SP - 1458-1466
IS - 6
VL - 54
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2005_Feldman,
author = {V I Feldman and F F Sukhov and A. Yu. Orlov and I V Tyulpina and E A Logacheva and D A Tyurin},
title = {Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals},
journal = {Russian Chemical Bulletin},
year = {2005},
volume = {54},
publisher = {Springer Nature},
month = {jun},
url = {http://link.springer.com/10.1007/s11172-005-0427-9},
number = {6},
pages = {1458--1466},
doi = {10.1007/s11172-005-0427-9}
}
Cite this
MLA
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Feldman, V. I., et al. “Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: Formation of xenon-containing molecules and radicals.” Russian Chemical Bulletin, vol. 54, no. 6, Jun. 2005, pp. 1458-1466. http://link.springer.com/10.1007/s11172-005-0427-9.
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