Springer Nature
Russian Chemical Bulletin
,  volume 54 ,  issue 7 ,  pages 1552-1556

Formation of Pt-S-Mn groups in platinum triphenylphosphine complexes with cymanthrenylthiolate ligands

Publication type: Journal Article
Publication date: 2005-07-01
Springer Nature
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Stepwise decarbonylation of the platinum complex with cymanthrenylthiolate ligands cis-(Ph3P)2Pt[(SC5H4)Mn(CO)3]2 (1) affords the cis-(Ph3P)2Pt[(SC5H4)Mn(CO)3]-[(SC5H4)Mn(CO)2] (2) and cis-(Ph3P)2Pt[(SC5H4)Mn(CO)2]2 (3) complexes. The replacement of one carbonyl group at the manganese atom with the lone electron pair of sulfur is accompanied by the formation of a new Mn-S bond giving rise to an unusual norbornane-type core. Complexes 1–3 were characterized by elemental analysis and IR spectroscopy. The structures of complexes 1–3 were established by single-crystal X-ray diffraction.
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Pasynskii A. A. et al. Formation of Pt-S-Mn groups in platinum triphenylphosphine complexes with cymanthrenylthiolate ligands // Russian Chemical Bulletin. 2005. Vol. 54. No. 7. pp. 1552-1556.
GOST all authors (up to 50) Copy
Pasynskii A. A., Skabitsky I. V., Torubaev Yu. V. Formation of Pt-S-Mn groups in platinum triphenylphosphine complexes with cymanthrenylthiolate ligands // Russian Chemical Bulletin. 2005. Vol. 54. No. 7. pp. 1552-1556.
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TY - JOUR
DO - 10.1007/s11172-006-0002-z
UR - http://link.springer.com/10.1007/s11172-006-0002-z
TI - Formation of Pt-S-Mn groups in platinum triphenylphosphine complexes with cymanthrenylthiolate ligands
T2 - Russian Chemical Bulletin
AU - Pasynskii, A A
AU - Skabitsky, I V
AU - Torubaev, Yu V
PY - 2005
DA - 2005/07/01
PB - Springer Nature
SP - 1552-1556
IS - 7
VL - 54
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2005_Pasynskii,
author = {A A Pasynskii and I V Skabitsky and Yu V Torubaev},
title = {Formation of Pt-S-Mn groups in platinum triphenylphosphine complexes with cymanthrenylthiolate ligands},
journal = {Russian Chemical Bulletin},
year = {2005},
volume = {54},
publisher = {Springer Nature},
month = {jul},
url = {http://link.springer.com/10.1007/s11172-006-0002-z},
number = {7},
pages = {1552--1556},
doi = {10.1007/s11172-006-0002-z}
}
MLA
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Pasynskii, A. A., et al. “Formation of Pt-S-Mn groups in platinum triphenylphosphine complexes with cymanthrenylthiolate ligands.” Russian Chemical Bulletin, vol. 54, no. 7, Jul. 2005, pp. 1552-1556. http://link.springer.com/10.1007/s11172-006-0002-z.