Springer Nature
Russian Chemical Bulletin
,  volume 54 ,  issue 7 ,  pages 1569-1579

Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition

Publication type: Journal Article
Publication date: 2005-07-01
Springer Nature
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
In the presence of Ba2+ ions, (benzothiazolyl)ethenylbenzocrown ether forms the stable sandwich complex 2L⋅Ba2+ with an unusual structure, in which the benzothiazole fragments are arranged one above the other. Irradiation of the sandwich complex with visible light induces stereoselective [2+2] cycloaddition giving rise to two “head-to-head” isomers of biscrown-cyclobutane. The addition of dibasic dicarboxylic acids that additionally stabilize the sandwich complex in a favorable conformation affects the isomer ratio of the cyclobutanes formed. The conformational equilibria for the sandwich complex and cyclobutanes were studied by 1H NMR spectroscopy.
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GOST Copy
Gromov S. P. et al. Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition // Russian Chemical Bulletin. 2005. Vol. 54. No. 7. pp. 1569-1579.
GOST all authors (up to 50) Copy
Gromov S. P., Vedernikov A., Fedorov Y., Fedorova O., Andryukhina E. N., Shepel N. E., Strelenko Y., Johnels D., Edlund U., Saltiel J., Alfimov M. Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition // Russian Chemical Bulletin. 2005. Vol. 54. No. 7. pp. 1569-1579.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s11172-006-0005-9
UR - http://link.springer.com/10.1007/s11172-006-0005-9
TI - Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition
T2 - Russian Chemical Bulletin
AU - Gromov, S P
AU - Vedernikov, A.I.
AU - Fedorov, Yu.V.
AU - Fedorova, O.A.
AU - Andryukhina, E N
AU - Shepel, N E
AU - Strelenko, Yu.A.
AU - Johnels, D
AU - Edlund, U.
AU - Saltiel, J
AU - Alfimov, M.V.
PY - 2005
DA - 2005/07/01
PB - Springer Nature
SP - 1569-1579
IS - 7
VL - 54
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2005_Gromov,
author = {S P Gromov and A.I. Vedernikov and Yu.V. Fedorov and O.A. Fedorova and E N Andryukhina and N E Shepel and Yu.A. Strelenko and D Johnels and U. Edlund and J Saltiel and M.V. Alfimov},
title = {Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition},
journal = {Russian Chemical Bulletin},
year = {2005},
volume = {54},
publisher = {Springer Nature},
month = {jul},
url = {http://link.springer.com/10.1007/s11172-006-0005-9},
number = {7},
pages = {1569--1579},
doi = {10.1007/s11172-006-0005-9}
}
MLA
Cite this
MLA Copy
Gromov, S. P., et al. “Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition.” Russian Chemical Bulletin, vol. 54, no. 7, Jul. 2005, pp. 1569-1579. http://link.springer.com/10.1007/s11172-006-0005-9.