Springer Nature
Russian Chemical Bulletin
,  том 54 ,  издание 7 ,  страницы 1569-1579

Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition

Тип публикации: Journal Article
Дата публикации: 2005-07-01
Springer Nature
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SJR: 0.272
CiteScore: 2.8
Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
In the presence of Ba2+ ions, (benzothiazolyl)ethenylbenzocrown ether forms the stable sandwich complex 2L⋅Ba2+ with an unusual structure, in which the benzothiazole fragments are arranged one above the other. Irradiation of the sandwich complex with visible light induces stereoselective [2+2] cycloaddition giving rise to two “head-to-head” isomers of biscrown-cyclobutane. The addition of dibasic dicarboxylic acids that additionally stabilize the sandwich complex in a favorable conformation affects the isomer ratio of the cyclobutanes formed. The conformational equilibria for the sandwich complex and cyclobutanes were studied by 1H NMR spectroscopy.
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Gromov S. P. et al. Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition // Russian Chemical Bulletin. 2005. Vol. 54. No. 7. pp. 1569-1579.
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Gromov S. P., Vedernikov A., Fedorov Y., Fedorova O., Andryukhina E. N., Shepel N. E., Strelenko Y., Johnels D., Edlund U., Saltiel J., Alfimov M. Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition // Russian Chemical Bulletin. 2005. Vol. 54. No. 7. pp. 1569-1579.
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TY - JOUR
DO - 10.1007/s11172-006-0005-9
UR - http://link.springer.com/10.1007/s11172-006-0005-9
TI - Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition
T2 - Russian Chemical Bulletin
AU - Gromov, S P
AU - Vedernikov, A.I.
AU - Fedorov, Yu.V.
AU - Fedorova, O.A.
AU - Andryukhina, E N
AU - Shepel, N E
AU - Strelenko, Yu.A.
AU - Johnels, D
AU - Edlund, U.
AU - Saltiel, J
AU - Alfimov, M.V.
PY - 2005
DA - 2005/07/01
PB - Springer Nature
SP - 1569-1579
IS - 7
VL - 54
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2005_Gromov,
author = {S P Gromov and A.I. Vedernikov and Yu.V. Fedorov and O.A. Fedorova and E N Andryukhina and N E Shepel and Yu.A. Strelenko and D Johnels and U. Edlund and J Saltiel and M.V. Alfimov},
title = {Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition},
journal = {Russian Chemical Bulletin},
year = {2005},
volume = {54},
publisher = {Springer Nature},
month = {jul},
url = {http://link.springer.com/10.1007/s11172-006-0005-9},
number = {7},
pages = {1569--1579},
doi = {10.1007/s11172-006-0005-9}
}
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Gromov, S. P., et al. “Self-assembly of a (benzothiazolyl)ethenylbenzocrown ether into a sandwich complex and stereoselective [2+2] photocycloaddition.” Russian Chemical Bulletin, vol. 54, no. 7, Jul. 2005, pp. 1569-1579. http://link.springer.com/10.1007/s11172-006-0005-9.
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