Cage complexes as a molecular scaffold for polyfunctional and polytopic systems: Synthesis of the first closo-borate iron(II) clathrochelate
2
V. I. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
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Publication type: Journal Article
Publication date: 2006-01-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The ribbed functionalization of the clathrochelate iron(II) tris-dioximates as a potential “molecular scaffold” for the synthesis of polyfunctional and polytopic complexes with closo-dodecaborate-anion substituents was performed. closo-Dodecaborate-substituted clathrochelate [FeBd2(Cl(B12H11NH)Gm)(BF)2]2− (where Bd2− is α-benzyldioxime dianion, Gm is glyoxime residue) dianion was prepared starting from dichloride clathrochelate FeBd2(Cl2Gm)(BF)2 precursor with amino-closo-dodecaborate (NBu4)[B12H11NH3] in the presence of potassium tert-amylate. This clathrochelate dianion was isolated as a tetra-n-butylammonium salt and characterized using elemental analysis, MALDI-TOF and PD mass, IR, UV-Vis, 57Fe Mössbauer spectra as well as by 1H, 11B and 13C{1H} NMR spectra.
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12
Total citations:
12
Citations from 2024:
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(16%)
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Voloshin Ya. Z. et al. Cage complexes as a molecular scaffold for polyfunctional and polytopic systems: Synthesis of the first closo-borate iron(II) clathrochelate // Russian Chemical Bulletin. 2006. Vol. 55. No. 1. pp. 22-25.
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Voloshin Ya. Z., Varzatskii O. A., Zhizhin K. Yu., Kuznetsov N. T., Bubnov Yu. N. Cage complexes as a molecular scaffold for polyfunctional and polytopic systems: Synthesis of the first closo-borate iron(II) clathrochelate // Russian Chemical Bulletin. 2006. Vol. 55. No. 1. pp. 22-25.
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TY - JOUR
DO - 10.1007/s11172-006-0210-6
UR - https://doi.org/10.1007/s11172-006-0210-6
TI - Cage complexes as a molecular scaffold for polyfunctional and polytopic systems: Synthesis of the first closo-borate iron(II) clathrochelate
T2 - Russian Chemical Bulletin
AU - Voloshin, Ya Z
AU - Varzatskii, O A
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
AU - Bubnov, Yu N
PY - 2006
DA - 2006/01/01
PB - Springer Nature
SP - 22-25
IS - 1
VL - 55
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2006_Voloshin,
author = {Ya Z Voloshin and O A Varzatskii and K Yu Zhizhin and N. T. Kuznetsov and Yu N Bubnov},
title = {Cage complexes as a molecular scaffold for polyfunctional and polytopic systems: Synthesis of the first closo-borate iron(II) clathrochelate},
journal = {Russian Chemical Bulletin},
year = {2006},
volume = {55},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/s11172-006-0210-6},
number = {1},
pages = {22--25},
doi = {10.1007/s11172-006-0210-6}
}
Cite this
MLA
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Voloshin, Ya. Z., et al. “Cage complexes as a molecular scaffold for polyfunctional and polytopic systems: Synthesis of the first closo-borate iron(II) clathrochelate.” Russian Chemical Bulletin, vol. 55, no. 1, Jan. 2006, pp. 22-25. https://doi.org/10.1007/s11172-006-0210-6.
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