1-Methylimidazol-2-yl-functionalized cyclopentadienyl titanium and zirconium complexes. Crystal structure of [η 5:η1- C5 H4 CPh2 CH2 -(1-MeC3 H 2 N2 )]TiCl3
D P Krutko
1
,
M V Borzov
1, 2
,
Long Yu Liao
1
,
Wan-Li Nie
2
,
A.V. Churakov
3
,
J. A. K. Howard
4
,
D A Lemenovskii
1
Publication type: Journal Article
Publication date: 2006-09-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The new side-chain functionalized cyclopentadienyl ligand LiC5H4CPh2CH2R (R is 1-methylimidazol-2-yl) as lithium salt 2, the trimethylsilyl derivative Me3SiC5H4CPh2CH2R (3), and the ligand in the CH form (4) were prepared starting from 6,6-diphenylfulvene and 1,2-dimethylimidazole lithiated at the 2-Me group (1) and then characterized. The half-sandwich complexes (η5:η 1-C5H4CPh2CH2R)TiCl3 (5) and (η5:η 1-C5H4CPh2CH2R)ZrCl3 (6) were synthesized. The molecular structure of complex 5 was established by X-ray diffraction. Complexes 5 and 6 exhibit dynamic behavior in solution associated with degenerate interconversion of the pseudo-six-membered metallacycle. For titanium complex 5 in a solvating solvent, a dynamic process due to intramolecular dissociation—coordination of the imidazole fragment was observed.
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Total citations:
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Citations from 2024:
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Krutko D. P. et al. 1-Methylimidazol-2-yl-functionalized cyclopentadienyl titanium and zirconium complexes. Crystal structure of [η 5:η1- C5H4CPh2CH2-(1-MeC3H 2N2)]TiCl3 // Russian Chemical Bulletin. 2006. Vol. 55. No. 9. pp. 1574-1580.
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Krutko D. P., Borzov M. V., Liao L. Yu., Nie W., Churakov A., Howard J. A. K., Lemenovskii D. A. 1-Methylimidazol-2-yl-functionalized cyclopentadienyl titanium and zirconium complexes. Crystal structure of [η 5:η1- C5H4CPh2CH2-(1-MeC3H 2N2)]TiCl3 // Russian Chemical Bulletin. 2006. Vol. 55. No. 9. pp. 1574-1580.
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TY - JOUR
DO - 10.1007/s11172-006-0456-z
UR - http://link.springer.com/10.1007/s11172-006-0456-z
TI - 1-Methylimidazol-2-yl-functionalized cyclopentadienyl titanium and zirconium complexes. Crystal structure of [η 5:η1- C5H4CPh2CH2-(1-MeC3H 2N2)]TiCl3
T2 - Russian Chemical Bulletin
AU - Krutko, D P
AU - Borzov, M V
AU - Liao, Long Yu
AU - Nie, Wan-Li
AU - Churakov, A.V.
AU - Howard, J. A. K.
AU - Lemenovskii, D A
PY - 2006
DA - 2006/09/01
PB - Springer Nature
SP - 1574-1580
IS - 9
VL - 55
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2006_Krutko,
author = {D P Krutko and M V Borzov and Long Yu Liao and Wan-Li Nie and A.V. Churakov and J. A. K. Howard and D A Lemenovskii},
title = {1-Methylimidazol-2-yl-functionalized cyclopentadienyl titanium and zirconium complexes. Crystal structure of [η 5:η1- C5H4CPh2CH2-(1-MeC3H 2N2)]TiCl3},
journal = {Russian Chemical Bulletin},
year = {2006},
volume = {55},
publisher = {Springer Nature},
month = {sep},
url = {http://link.springer.com/10.1007/s11172-006-0456-z},
number = {9},
pages = {1574--1580},
doi = {10.1007/s11172-006-0456-z}
}
Cite this
MLA
Copy
Krutko, D. P., et al. “1-Methylimidazol-2-yl-functionalized cyclopentadienyl titanium and zirconium complexes. Crystal structure of [η 5:η1- C5H4CPh2CH2-(1-MeC3H 2N2)]TiCl3.” Russian Chemical Bulletin, vol. 55, no. 9, Sep. 2006, pp. 1574-1580. http://link.springer.com/10.1007/s11172-006-0456-z.