volume 56 issue 5 pages 993-1002

Synthesis of nitro and amino derivatives of benzothiacrown ethers

Publication typeJournal Article
Publication date2007-05-01
scimago Q3
SJR0.305
CiteScore2.8
Impact factor
ISSN10665285, 15739171
General Chemistry
Abstract
The condensation reaction of 1,2-bis(2-haloethoxy)-4-nitrobenzenes with acyclic α,ω-(oxa)alkanedithiols in the presence of alkali metal carbonates produced a series of nitrobenzodithiacrown ethers with macrocycles of different size. The structures of three ethers were established by X-ray diffraction. A new method was developed for the synthesis of nitrobenzomonothia-15-crown-5 ether. Nitro derivatives of benzodithiacrown ethers were tested as reagents for extraction of palladium(II), platinum(IV), and rhodium(III) from hydrochloric acid solutions. Extraction of PdII salts was found to be highly selective compared to that of PtIV and RhIII salts. Benzodithia-15-crown-5 ether is the most efficient extractant for palladium(II). Reduction of nitrobenzothiacrown ethers with hydrazine hydrate in the presence of a platinum catalyst afforded their amino derivatives.
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GOST Copy
Dmitrieva S. N. et al. Synthesis of nitro and amino derivatives of benzothiacrown ethers // Russian Chemical Bulletin. 2007. Vol. 56. No. 5. pp. 993-1002.
GOST all authors (up to 50) Copy
Dmitrieva S. N., Sidorenko N. I., Vedernikov A., Kuz'mina L. G., Howard J. A. K., Buslaeva T. M., Gromov S. P. Synthesis of nitro and amino derivatives of benzothiacrown ethers // Russian Chemical Bulletin. 2007. Vol. 56. No. 5. pp. 993-1002.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s11172-007-0150-9
UR - http://link.springer.com/10.1007/s11172-007-0150-9
TI - Synthesis of nitro and amino derivatives of benzothiacrown ethers
T2 - Russian Chemical Bulletin
AU - Dmitrieva, S N
AU - Sidorenko, N I
AU - Vedernikov, A.I.
AU - Kuz'mina, L. G.
AU - Howard, J. A. K.
AU - Buslaeva, T M
AU - Gromov, S P
PY - 2007
DA - 2007/05/01
PB - Springer Nature
SP - 993-1002
IS - 5
VL - 56
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2007_Dmitrieva,
author = {S N Dmitrieva and N I Sidorenko and A.I. Vedernikov and L. G. Kuz'mina and J. A. K. Howard and T M Buslaeva and S P Gromov},
title = {Synthesis of nitro and amino derivatives of benzothiacrown ethers},
journal = {Russian Chemical Bulletin},
year = {2007},
volume = {56},
publisher = {Springer Nature},
month = {may},
url = {http://link.springer.com/10.1007/s11172-007-0150-9},
number = {5},
pages = {993--1002},
doi = {10.1007/s11172-007-0150-9}
}
MLA
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MLA Copy
Dmitrieva, S. N., et al. “Synthesis of nitro and amino derivatives of benzothiacrown ethers.” Russian Chemical Bulletin, vol. 56, no. 5, May. 2007, pp. 993-1002. http://link.springer.com/10.1007/s11172-007-0150-9.