New approach to the synthesis of trifluoromethylvinyl sulfides
Тип публикации: Journal Article
Дата публикации: 2007-08-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
Nucleophilic substitution reaction of halogen atom in β-chloro-and β-bromo-β-trifluoromethylstyrenes by thiolates was studied. Stereo-and regioselectivity of the reaction with respect to the electronic and sterical properties of substituents in the aromatic ring of starting styrenes was investigated. Regioisomer with geminal trifluoromethyl and alkyl-or arylthio groups was found to be formed predominantly or exclusively. The reaction proceeds stereoselectively in nearly quantitative yields. On this basis, a new convenient stereoselective method for the synthesis of trifluoromethylvinyl sulfides was elaborated.
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ГОСТ
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Muzalevskiy V. M. et al. New approach to the synthesis of trifluoromethylvinyl sulfides // Russian Chemical Bulletin. 2007. Vol. 56. No. 8. pp. 1526-1533.
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Muzalevskiy V. M., Shastin A. V., Balenkova E. S., Nenajdenko V. G. New approach to the synthesis of trifluoromethylvinyl sulfides // Russian Chemical Bulletin. 2007. Vol. 56. No. 8. pp. 1526-1533.
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TY - JOUR
DO - 10.1007/s11172-007-0236-4
UR - https://doi.org/10.1007/s11172-007-0236-4
TI - New approach to the synthesis of trifluoromethylvinyl sulfides
T2 - Russian Chemical Bulletin
AU - Muzalevskiy, V M
AU - Shastin, A V
AU - Balenkova, E S
AU - Nenajdenko, V G
PY - 2007
DA - 2007/08/01
PB - Springer Nature
SP - 1526-1533
IS - 8
VL - 56
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (до 50 авторов)
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@article{2007_Muzalevskiy,
author = {V M Muzalevskiy and A V Shastin and E S Balenkova and V G Nenajdenko},
title = {New approach to the synthesis of trifluoromethylvinyl sulfides},
journal = {Russian Chemical Bulletin},
year = {2007},
volume = {56},
publisher = {Springer Nature},
month = {aug},
url = {https://doi.org/10.1007/s11172-007-0236-4},
number = {8},
pages = {1526--1533},
doi = {10.1007/s11172-007-0236-4}
}
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MLA
Скопировать
Muzalevskiy, V. M., et al. “New approach to the synthesis of trifluoromethylvinyl sulfides.” Russian Chemical Bulletin, vol. 56, no. 8, Aug. 2007, pp. 1526-1533. https://doi.org/10.1007/s11172-007-0236-4.