Silicon- and germanium-substituted propynals as ambident electrophiles for the design of new heterocycles and polyfunctional acetylenes
Тип публикации: Journal Article
Дата публикации: 2008-05-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
Research results on the reactivity of silicon- and germanium-substituted propynals as ambident electrophiles in the reactions with mono- and binucleophiles were summarized. Chemo- and regioselectivity of the nucleophilic addition and cycloaddition depending on the structure of propynals, the nature of a reagent, catalyst, and the reaction conditions was studied. Wide synthetic potentialities of substituted propynals in the synthesis of new heterocyclic systems and polyfunctional acetylenes were demonstrated.
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Medvedeva A. S., Mareev A. V., Demina M. M. Silicon- and germanium-substituted propynals as ambident electrophiles for the design of new heterocycles and polyfunctional acetylenes // Russian Chemical Bulletin. 2008. Vol. 57. No. 5. pp. 929-946.
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Medvedeva A. S., Mareev A. V., Demina M. M. Silicon- and germanium-substituted propynals as ambident electrophiles for the design of new heterocycles and polyfunctional acetylenes // Russian Chemical Bulletin. 2008. Vol. 57. No. 5. pp. 929-946.
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TY - JOUR
DO - 10.1007/s11172-008-0128-2
UR - https://doi.org/10.1007/s11172-008-0128-2
TI - Silicon- and germanium-substituted propynals as ambident electrophiles for the design of new heterocycles and polyfunctional acetylenes
T2 - Russian Chemical Bulletin
AU - Medvedeva, A S
AU - Mareev, A V
AU - Demina, M M
PY - 2008
DA - 2008/05/01
PB - Springer Nature
SP - 929-946
IS - 5
VL - 57
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2008_Medvedeva,
author = {A S Medvedeva and A V Mareev and M M Demina},
title = {Silicon- and germanium-substituted propynals as ambident electrophiles for the design of new heterocycles and polyfunctional acetylenes},
journal = {Russian Chemical Bulletin},
year = {2008},
volume = {57},
publisher = {Springer Nature},
month = {may},
url = {https://doi.org/10.1007/s11172-008-0128-2},
number = {5},
pages = {929--946},
doi = {10.1007/s11172-008-0128-2}
}
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Medvedeva, A. S., et al. “Silicon- and germanium-substituted propynals as ambident electrophiles for the design of new heterocycles and polyfunctional acetylenes.” Russian Chemical Bulletin, vol. 57, no. 5, May. 2008, pp. 929-946. https://doi.org/10.1007/s11172-008-0128-2.