Springer Nature
Russian Chemical Bulletin
,  volume 58 ,  issue 1 ,  pages 108-114

Stereoselective [2+2] photocycloaddition in bispseudosandwich complexes of bis(18-crown-6) stilbene with alkanediammonium ions

Publication type: Journal Article
Publication date: 2009-01-01
Springer Nature
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Due to hydrogen bonding, bis(18-crown-6) stilbene forms 1 : 1, 1 : 2, and 2 : 2 complexes with H3N+(CH2)nNH3+ 2ClO4− salts (n = 2—10, 12). The length of the polymethylene chain in the diammonium ions affects the phototransformation direction of stilbene and the composition of the products. In the 2: 2 bispseudosandwich complexes with relatively short alkanediammonium ions (n = 2—4), the stereoselective reaction of [2+2] photocycloaddition proceeds to form mainly the rctt-isomer of the cyclobutane derivative. The structure of rctt-cyclobutane derivative as a complex with H3N+(CH2)4NH3+2ClO4- was confirmed by X-ray diffraction analysis.
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Gromov S. P. et al. Stereoselective [2+2] photocycloaddition in bispseudosandwich complexes of bis(18-crown-6) stilbene with alkanediammonium ions // Russian Chemical Bulletin. 2009. Vol. 58. No. 1. pp. 108-114.
GOST all authors (up to 50) Copy
Gromov S. P., Vedernikov A., Kuz'mina L. G., Lobova N., Basok S. S., Strelenko Y., Alfimov M. Stereoselective [2+2] photocycloaddition in bispseudosandwich complexes of bis(18-crown-6) stilbene with alkanediammonium ions // Russian Chemical Bulletin. 2009. Vol. 58. No. 1. pp. 108-114.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1007/s11172-009-0016-4
UR - http://link.springer.com/10.1007/s11172-009-0016-4
TI - Stereoselective [2+2] photocycloaddition in bispseudosandwich complexes of bis(18-crown-6) stilbene with alkanediammonium ions
T2 - Russian Chemical Bulletin
AU - Gromov, S P
AU - Vedernikov, A.I.
AU - Kuz'mina, L. G.
AU - Lobova, N.A.
AU - Basok, S S
AU - Strelenko, Yu.A.
AU - Alfimov, M.V.
PY - 2009
DA - 2009/01/01
PB - Springer Nature
SP - 108-114
IS - 1
VL - 58
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2009_Gromov,
author = {S P Gromov and A.I. Vedernikov and L. G. Kuz'mina and N.A. Lobova and S S Basok and Yu.A. Strelenko and M.V. Alfimov},
title = {Stereoselective [2+2] photocycloaddition in bispseudosandwich complexes of bis(18-crown-6) stilbene with alkanediammonium ions},
journal = {Russian Chemical Bulletin},
year = {2009},
volume = {58},
publisher = {Springer Nature},
month = {jan},
url = {http://link.springer.com/10.1007/s11172-009-0016-4},
number = {1},
pages = {108--114},
doi = {10.1007/s11172-009-0016-4}
}
MLA
Cite this
MLA Copy
Gromov, S. P., et al. “Stereoselective [2+2] photocycloaddition in bispseudosandwich complexes of bis(18-crown-6) stilbene with alkanediammonium ions.” Russian Chemical Bulletin, vol. 58, no. 1, Jan. 2009, pp. 108-114. http://link.springer.com/10.1007/s11172-009-0016-4.