volume 58 issue 6 pages 1211-1216

Stereospecific [2+2] autophotocycloaddition in the dimeric complex of 18-crown-6 ether styryl dye bearing N-(3-ammoniopropyl) substituent

Publication typeJournal Article
Publication date2009-06-01
scimago Q3
SJR0.305
CiteScore2.8
Impact factor
ISSN10665285, 15739171
General Chemistry
Abstract
New 18-crown-6 ether styryl dye of the 4-pyridine series bearing N-(3-ammoniopropyl) substituent has been synthesized. In MeCN, the dye forms a stable dimeric complex of the syn-head-to-tail type due to the complexation of the ammonium group of one molecule with the crown ether fragment of another. In the dimeric complex, the ethylene bonds of the molecules are close in space and antiparallel, which promotes an efficient stereospecific [2+2] autophotocycloaddition to yield the only rctt-isomer of 1,2,3,4-tetrasubstituted cyclobutane. The cyclobutane derivative structure was confirmed by NMR spectroscopy and X-ray diffraction.
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Gromov S. P. et al. Stereospecific [2+2] autophotocycloaddition in the dimeric complex of 18-crown-6 ether styryl dye bearing N-(3-ammoniopropyl) substituent // Russian Chemical Bulletin. 2009. Vol. 58. No. 6. pp. 1211-1216.
GOST all authors (up to 50) Copy
Gromov S. P., Lobova N., Vedernikov A., Kuz'mina L. G., Howard J. A. K., Alfimov M. Stereospecific [2+2] autophotocycloaddition in the dimeric complex of 18-crown-6 ether styryl dye bearing N-(3-ammoniopropyl) substituent // Russian Chemical Bulletin. 2009. Vol. 58. No. 6. pp. 1211-1216.
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RIS Copy
TY - JOUR
DO - 10.1007/s11172-009-0156-6
UR - http://link.springer.com/10.1007/s11172-009-0156-6
TI - Stereospecific [2+2] autophotocycloaddition in the dimeric complex of 18-crown-6 ether styryl dye bearing N-(3-ammoniopropyl) substituent
T2 - Russian Chemical Bulletin
AU - Gromov, S P
AU - Lobova, N.A.
AU - Vedernikov, A.I.
AU - Kuz'mina, L. G.
AU - Howard, J. A. K.
AU - Alfimov, M.V.
PY - 2009
DA - 2009/06/01
PB - Springer Nature
SP - 1211-1216
IS - 6
VL - 58
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2009_Gromov,
author = {S P Gromov and N.A. Lobova and A.I. Vedernikov and L. G. Kuz'mina and J. A. K. Howard and M.V. Alfimov},
title = {Stereospecific [2+2] autophotocycloaddition in the dimeric complex of 18-crown-6 ether styryl dye bearing N-(3-ammoniopropyl) substituent},
journal = {Russian Chemical Bulletin},
year = {2009},
volume = {58},
publisher = {Springer Nature},
month = {jun},
url = {http://link.springer.com/10.1007/s11172-009-0156-6},
number = {6},
pages = {1211--1216},
doi = {10.1007/s11172-009-0156-6}
}
MLA
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MLA Copy
Gromov, S. P., et al. “Stereospecific [2+2] autophotocycloaddition in the dimeric complex of 18-crown-6 ether styryl dye bearing N-(3-ammoniopropyl) substituent.” Russian Chemical Bulletin, vol. 58, no. 6, Jun. 2009, pp. 1211-1216. http://link.springer.com/10.1007/s11172-009-0156-6.