Nucleophilic addition of alcohols to the C-N multiple bonds of the nitrilium substituent in the anion [2-B10H9(N≡CMe)]−
A P Zhdanov
1
,
M V Lisovsky
1
,
L. V. Goeva
1
,
G A Razgonyaeva
1
,
I N Polyakova
1
,
K Yu Zhizhin
1
,
N. T. Kuznetsov
1
Publication type: Journal Article
Publication date: 2009-08-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reactions of salts of the anion [2-B10H9(N≡CMe)]− with aliphatic alcohols ROH (R = C n H2n+1 (n = 1–6) CH2CH2(OEt), Pri, Bui, But, i-C5H11) are studied. These reactions result in hydrolytically stable imidates [2-B10H9{NH=C(OR)Me}]−. Their structures were confirmed by the data from mass spectrometry, IR, 1H, 11B, and 13C NMR spectroscopy. The molecular geometry of [2(Z)-B10H9{NH=C(OBu)Me}]−, which formed in nucleophilic addition reaction of n-butyl alcohol to [2-B10H9(N≡CMe)]−, was established by X-ray diffraction analysis.
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Total citations:
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Citations from 2024:
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GOST
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Zhdanov A. P. et al. Nucleophilic addition of alcohols to the C-N multiple bonds of the nitrilium substituent in the anion [2-B10H9(N≡CMe)]− // Russian Chemical Bulletin. 2009. Vol. 58. No. 8. pp. 1694-1700.
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Zhdanov A. P., Lisovsky M. V., Goeva L. V., Razgonyaeva G. A., Polyakova I. N., Zhizhin K. Yu., Kuznetsov N. T. Nucleophilic addition of alcohols to the C-N multiple bonds of the nitrilium substituent in the anion [2-B10H9(N≡CMe)]− // Russian Chemical Bulletin. 2009. Vol. 58. No. 8. pp. 1694-1700.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s11172-009-0234-9
UR - https://doi.org/10.1007/s11172-009-0234-9
TI - Nucleophilic addition of alcohols to the C-N multiple bonds of the nitrilium substituent in the anion [2-B10H9(N≡CMe)]−
T2 - Russian Chemical Bulletin
AU - Zhdanov, A P
AU - Lisovsky, M V
AU - Goeva, L. V.
AU - Razgonyaeva, G A
AU - Polyakova, I N
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2009
DA - 2009/08/01
PB - Springer Nature
SP - 1694-1700
IS - 8
VL - 58
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2009_Zhdanov,
author = {A P Zhdanov and M V Lisovsky and L. V. Goeva and G A Razgonyaeva and I N Polyakova and K Yu Zhizhin and N. T. Kuznetsov},
title = {Nucleophilic addition of alcohols to the C-N multiple bonds of the nitrilium substituent in the anion [2-B10H9(N≡CMe)]−},
journal = {Russian Chemical Bulletin},
year = {2009},
volume = {58},
publisher = {Springer Nature},
month = {aug},
url = {https://doi.org/10.1007/s11172-009-0234-9},
number = {8},
pages = {1694--1700},
doi = {10.1007/s11172-009-0234-9}
}
Cite this
MLA
Copy
Zhdanov, A. P., et al. “Nucleophilic addition of alcohols to the C-N multiple bonds of the nitrilium substituent in the anion [2-B10H9(N≡CMe)]−.” Russian Chemical Bulletin, vol. 58, no. 8, Aug. 2009, pp. 1694-1700. https://doi.org/10.1007/s11172-009-0234-9.
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