Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine
Publication type: Journal Article
Publication date: 2009-09-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
A quaternary 4-styrylpyridinium salt having the N-ammoniopropyl substituent forms a pseudodimeric head-to-tail complex with neutral 18-crown-6-containing 4-styrylpyridine in MeCN through H-bonding. This complex undergoes stereospecific [2+2] photocycloaddition due to preorganization of the ethylene bonds in the syn-arranged chromophoric fragments of the components. The structure of the rctt-isomer of the cyclobutane derivative obtained was established by NMR spectroscopy and X-ray diffraction analysis.
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Vedernikov A. et al. Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine // Russian Chemical Bulletin. 2009. Vol. 58. No. 9. pp. 1955-1961.
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Vedernikov A., Sazonov S. K., Kuz'mina L. G., Howard J. A. K., Alfimov M., Gromov S. P. Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine // Russian Chemical Bulletin. 2009. Vol. 58. No. 9. pp. 1955-1961.
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TY - JOUR
DO - 10.1007/s11172-009-0267-0
UR - http://link.springer.com/10.1007/s11172-009-0267-0
TI - Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine
T2 - Russian Chemical Bulletin
AU - Vedernikov, A.I.
AU - Sazonov, S K
AU - Kuz'mina, L. G.
AU - Howard, J. A. K.
AU - Alfimov, M.V.
AU - Gromov, S P
PY - 2009
DA - 2009/09/01
PB - Springer Nature
SP - 1955-1961
IS - 9
VL - 58
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2009_Vedernikov,
author = {A.I. Vedernikov and S K Sazonov and L. G. Kuz'mina and J. A. K. Howard and M.V. Alfimov and S P Gromov},
title = {Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine},
journal = {Russian Chemical Bulletin},
year = {2009},
volume = {58},
publisher = {Springer Nature},
month = {sep},
url = {http://link.springer.com/10.1007/s11172-009-0267-0},
number = {9},
pages = {1955--1961},
doi = {10.1007/s11172-009-0267-0}
}
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MLA
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Vedernikov, A.I., et al. “Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine.” Russian Chemical Bulletin, vol. 58, no. 9, Sep. 2009, pp. 1955-1961. http://link.springer.com/10.1007/s11172-009-0267-0.
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