Russian Chemical Bulletin

, том 58 , издание 9 , страницы 1955-1961

Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine

Тип публикации: Journal Article

Дата публикации: 2009-09-01

Springer Nature

Russian Chemical Bulletin

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SJR: 0.305

CiteScore: 2.8

Impact factor: 1.7

ISSN: 10665285, 15739171

DOI: 10.1007/s11172-009-0267-0

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General Chemistry

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A quaternary 4-styrylpyridinium salt having the N-ammoniopropyl substituent forms a pseudodimeric head-to-tail complex with neutral 18-crown-6-containing 4-styrylpyridine in MeCN through H-bonding. This complex undergoes stereospecific [2+2] photocycloaddition due to preorganization of the ethylene bonds in the syn-arranged chromophoric fragments of the components. The structure of the rctt-isomer of the cyclobutane derivative obtained was established by NMR spectroscopy and X-ray diffraction analysis.

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Vedernikov A. et al. Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine // Russian Chemical Bulletin. 2009. Vol. 58. No. 9. pp. 1955-1961.

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Vedernikov A., Sazonov S. K., Kuz'mina L. G., Howard J. A. K., Alfimov M., Gromov S. P. Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine // Russian Chemical Bulletin. 2009. Vol. 58. No. 9. pp. 1955-1961.

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TY - JOUR

DO - 10.1007/s11172-009-0267-0

UR - http://link.springer.com/10.1007/s11172-009-0267-0

TI - Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine

T2 - Russian Chemical Bulletin

AU - Vedernikov, A.I.

AU - Sazonov, S K

AU - Kuz'mina, L. G.

AU - Howard, J. A. K.

AU - Alfimov, M.V.

AU - Gromov, S P

PY - 2009

DA - 2009/09/01

PB - Springer Nature

SP - 1955-1961

IS - 9

VL - 58

SN - 1066-5285

SN - 1573-9171

ER -

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@article{2009_Vedernikov,

author = {A.I. Vedernikov and S K Sazonov and L. G. Kuz'mina and J. A. K. Howard and M.V. Alfimov and S P Gromov},

title = {Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine},

journal = {Russian Chemical Bulletin},

year = {2009},

volume = {58},

publisher = {Springer Nature},

month = {sep},

url = {http://link.springer.com/10.1007/s11172-009-0267-0},

number = {9},

pages = {1955--1961},

doi = {10.1007/s11172-009-0267-0}

}

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Vedernikov, A.I., et al. “Stereospecific [2+2] photocycloaddition in a pseudodimeric complex between N-ammoniopropylstyrylpyridine and 18-crown-6-containing styrylpyridine.” Russian Chemical Bulletin, vol. 58, no. 9, Sep. 2009, pp. 1955-1961. http://link.springer.com/10.1007/s11172-009-0267-0.