Springer Nature
Russian Chemical Bulletin
,  volume 59 ,  issue 2 ,  pages 329-336

New 1,3-disubstituted side-chain functionalized indenyl ligands and zirconium complexes derived from them

Publication type: Journal Article
Publication date: 2010-02-01
Springer Nature
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
New functionalized indenyl ligands IndX = 1,3-C9H5(Pri)(CH2CH2X) (X = OMe or NMe2) and 1,3-C9H5(Pri)[CMe2CH2(2′-py)] and the zirconium sandwich complexes (IndX)Cp*ZrCl2 (Cp* is pentamethylcyclopentadienyl) were synthesized. The photochemical behavior and the reduction reactions of zirconocene dichlorides were investigated. The properties of these compounds are determined mainly by the high lability of Zr-Ind bonds. The reduction of (IndX)Cp*ZrCl2 (X = NMe2) selectively affords the complex Cp*[η5:η2-(C,N)-C9H5(Pri)CH2CH2N(Me)CH2]ZrH as the intramolecular NCH2-H bond activation product. The molecular structures of the complex (IndX)Cp*ZrCl2 (X = OMe) and its photochemical decomposition product [Cp*ZrCl2(OMe)]2 were established by X-ray diffraction.
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Krutko D. P. et al. New 1,3-disubstituted side-chain functionalized indenyl ligands and zirconium complexes derived from them // Russian Chemical Bulletin. 2010. Vol. 59. No. 2. pp. 329-336.
GOST all authors (up to 50) Copy
Krutko D. P., Belov S., Kirsanov R. S., Lemenovskii D. A., Churakov A. New 1,3-disubstituted side-chain functionalized indenyl ligands and zirconium complexes derived from them // Russian Chemical Bulletin. 2010. Vol. 59. No. 2. pp. 329-336.
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TY - JOUR
DO - 10.1007/s11172-010-0083-6
UR - http://link.springer.com/10.1007/s11172-010-0083-6
TI - New 1,3-disubstituted side-chain functionalized indenyl ligands and zirconium complexes derived from them
T2 - Russian Chemical Bulletin
AU - Krutko, D P
AU - Belov, S.A.
AU - Kirsanov, R S
AU - Lemenovskii, D A
AU - Churakov, A.V.
PY - 2010
DA - 2010/02/01
PB - Springer Nature
SP - 329-336
IS - 2
VL - 59
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2010_Krutko,
author = {D P Krutko and S.A. Belov and R S Kirsanov and D A Lemenovskii and A.V. Churakov},
title = {New 1,3-disubstituted side-chain functionalized indenyl ligands and zirconium complexes derived from them},
journal = {Russian Chemical Bulletin},
year = {2010},
volume = {59},
publisher = {Springer Nature},
month = {feb},
url = {http://link.springer.com/10.1007/s11172-010-0083-6},
number = {2},
pages = {329--336},
doi = {10.1007/s11172-010-0083-6}
}
MLA
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Krutko, D. P., et al. “New 1,3-disubstituted side-chain functionalized indenyl ligands and zirconium complexes derived from them.” Russian Chemical Bulletin, vol. 59, no. 2, Feb. 2010, pp. 329-336. http://link.springer.com/10.1007/s11172-010-0083-6.