Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations
V M Retivov
1, 2
,
E Yu Matveev
1, 2
,
M V Lisovskiy
1
,
G A Razgonyaeva
1
,
L. I. OCHERTYANOVA
1
,
K Yu Zhizhin
1, 2
,
N. T. Kuznetsov
1, 2
Publication type: Journal Article
Publication date: 2010-03-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Nucleophilic substitution at the exo-polyhedral boron atoms of claso-decaborate [B10H10]2- in the presence of carbocations, which were generated in situ from various halocarbons (triphe-nylmethyl chloride, 1-bromoadamantan, n-butyl bromide), was studied. The reactions carried out in nucleophilic solvents (cyclic ethers and thioethers, N,N-disubstituted amides, and car-boxylic acids) and in the presence of halocarbons afforded mono-and disubstituted compounds with the exo-polyhedral B—O and B—S bonds, which contained a molecule of the solvent as substituent. The structures of the compounds synthesized were confirmed by the IR, mass, and 1H, 11B, and 13C NMR spectra.
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Total citations:
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Citations from 2024:
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(23.52%)
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GOST
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Retivov V. M. et al. Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations // Russian Chemical Bulletin. 2010. Vol. 59. No. 3. pp. 550-555.
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Retivov V. M., Matveev E. Yu., Lisovskiy M. V., Razgonyaeva G. A., OCHERTYANOVA L. I., Zhizhin K. Yu., Kuznetsov N. T. Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations // Russian Chemical Bulletin. 2010. Vol. 59. No. 3. pp. 550-555.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s11172-010-0123-2
UR - https://doi.org/10.1007/s11172-010-0123-2
TI - Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations
T2 - Russian Chemical Bulletin
AU - Retivov, V M
AU - Matveev, E Yu
AU - Lisovskiy, M V
AU - Razgonyaeva, G A
AU - OCHERTYANOVA, L. I.
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2010
DA - 2010/03/01
PB - Springer Nature
SP - 550-555
IS - 3
VL - 59
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2010_Retivov,
author = {V M Retivov and E Yu Matveev and M V Lisovskiy and G A Razgonyaeva and L. I. OCHERTYANOVA and K Yu Zhizhin and N. T. Kuznetsov},
title = {Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations},
journal = {Russian Chemical Bulletin},
year = {2010},
volume = {59},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/s11172-010-0123-2},
number = {3},
pages = {550--555},
doi = {10.1007/s11172-010-0123-2}
}
Cite this
MLA
Copy
Retivov, V. M., et al. “Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations.” Russian Chemical Bulletin, vol. 59, no. 3, Mar. 2010, pp. 550-555. https://doi.org/10.1007/s11172-010-0123-2.
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