Springer Nature
Russian Chemical Bulletin
,  том 59 ,  издание 3 ,  страницы 550-555

Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations

Тип публикации: Journal Article
Дата публикации: 2010-03-01
Springer Nature
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SJR: 0.272
CiteScore: 2.8
Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
Nucleophilic substitution at the exo-polyhedral boron atoms of claso-decaborate [B10H10]2- in the presence of carbocations, which were generated in situ from various halocarbons (triphe-nylmethyl chloride, 1-bromoadamantan, n-butyl bromide), was studied. The reactions carried out in nucleophilic solvents (cyclic ethers and thioethers, N,N-disubstituted amides, and car-boxylic acids) and in the presence of halocarbons afforded mono-and disubstituted compounds with the exo-polyhedral B—O and B—S bonds, which contained a molecule of the solvent as substituent. The structures of the compounds synthesized were confirmed by the IR, mass, and 1H, 11B, and 13C NMR spectra.
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Retivov V. M. et al. Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations // Russian Chemical Bulletin. 2010. Vol. 59. No. 3. pp. 550-555.
ГОСТ со всеми авторами (до 50) Скопировать
Retivov V. M., Matveev E. Yu., Lisovskiy M. V., Razgonyaeva G. A., OCHERTYANOVA L. I., Zhizhin K. Yu., Kuznetsov N. T. Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations // Russian Chemical Bulletin. 2010. Vol. 59. No. 3. pp. 550-555.
RIS |
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TY - JOUR
DO - 10.1007/s11172-010-0123-2
UR - https://doi.org/10.1007/s11172-010-0123-2
TI - Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations
T2 - Russian Chemical Bulletin
AU - Retivov, V M
AU - Matveev, E Yu
AU - Lisovskiy, M V
AU - Razgonyaeva, G A
AU - OCHERTYANOVA, L. I.
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2010
DA - 2010/03/01
PB - Springer Nature
SP - 550-555
IS - 3
VL - 59
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
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@article{2010_Retivov,
author = {V M Retivov and E Yu Matveev and M V Lisovskiy and G A Razgonyaeva and L. I. OCHERTYANOVA and K Yu Zhizhin and N. T. Kuznetsov},
title = {Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations},
journal = {Russian Chemical Bulletin},
year = {2010},
volume = {59},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/s11172-010-0123-2},
number = {3},
pages = {550--555},
doi = {10.1007/s11172-010-0123-2}
}
MLA
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Retivov, V. M., et al. “Nucleophilic substitution in closo-decaborate [B10H10]2− in the presence of carbocations.” Russian Chemical Bulletin, vol. 59, no. 3, Mar. 2010, pp. 550-555. https://doi.org/10.1007/s11172-010-0123-2.
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