Donor-acceptor complexes of dipyrrolylmethenes with boron trifluoride as intermediates in the synthesis of Bodipy
Publication type: Journal Article
Publication date: 2010-10-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The formation of donor-acceptor complexes of dipyrrolylmethene and structurally similar biladiene-a,c with boron trifluoride was studied by electronic absorption, IR, and 1H NMR spectroscopies as well as by quantum chemical calculations. It was shown that the formation of donor-acceptor complexes is the first step of the synthesis of the corresponding boron fluoride chelate complexes (Bodipy). The hydrogen bond N—H...F—B additionaly stabilizes the donor-acceptor complexes. The stability constants, geometric parameters, and energy characteristics of the donoracceptor complexes were determined; the two-step mechanism of Bodipy synthesis was analyzed.
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Rumyantsev E. V., Marfin Yu. S., Antina E. V. Donor-acceptor complexes of dipyrrolylmethenes with boron trifluoride as intermediates in the synthesis of Bodipy // Russian Chemical Bulletin. 2010. Vol. 59. No. 10. pp. 1890-1895.
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Rumyantsev E. V., Marfin Yu. S., Antina E. V. Donor-acceptor complexes of dipyrrolylmethenes with boron trifluoride as intermediates in the synthesis of Bodipy // Russian Chemical Bulletin. 2010. Vol. 59. No. 10. pp. 1890-1895.
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RIS
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TY - JOUR
DO - 10.1007/s11172-010-0329-3
UR - https://doi.org/10.1007/s11172-010-0329-3
TI - Donor-acceptor complexes of dipyrrolylmethenes with boron trifluoride as intermediates in the synthesis of Bodipy
T2 - Russian Chemical Bulletin
AU - Rumyantsev, E V
AU - Marfin, Yu S
AU - Antina, E V
PY - 2010
DA - 2010/10/01
PB - Springer Nature
SP - 1890-1895
IS - 10
VL - 59
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2010_Rumyantsev,
author = {E V Rumyantsev and Yu S Marfin and E V Antina},
title = {Donor-acceptor complexes of dipyrrolylmethenes with boron trifluoride as intermediates in the synthesis of Bodipy},
journal = {Russian Chemical Bulletin},
year = {2010},
volume = {59},
publisher = {Springer Nature},
month = {oct},
url = {https://doi.org/10.1007/s11172-010-0329-3},
number = {10},
pages = {1890--1895},
doi = {10.1007/s11172-010-0329-3}
}
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MLA
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Rumyantsev, E. V., et al. “Donor-acceptor complexes of dipyrrolylmethenes with boron trifluoride as intermediates in the synthesis of Bodipy.” Russian Chemical Bulletin, vol. 59, no. 10, Oct. 2010, pp. 1890-1895. https://doi.org/10.1007/s11172-010-0329-3.
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