Russian Chemical Bulletin

, volume 60 , issue 1 , pages 99-106

Cp2ZrCl2-Catalyzed cycloalumination of acetylenic alcohols and propargylamines by Et3Al

I R Ramazanov ¹

R N Kadikova ¹

U M Dzhemilev ¹

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Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, Russian Federation |

Publication type: Journal Article

Publication date: 2011-01-01

Springer Nature

Russian Chemical Bulletin

scimago Q3

SJR: 0.305

CiteScore: 2.8

Impact factor: —

ISSN: 10665285, 15739171

DOI: 10.1007/s11172-011-0013-2

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General Chemistry

Abstract

The Cp2ZrCl2-catalyzed cycloalumination of acetylenic alcohols and propargylamines by Et3Al was studied. The process affords 2,3-disubstituted alumacyclopent-2-enes, which were identified by the analysis of the products of their deuterolysis and hydrolysis. The cycloalumination of alkyl- and phenyl-substituted propargylamines proceeds with high regio- and stereoselectivity to give the corresponding allylamine derivatives in high yield. Unlike the phenyl derivatives, the cycloalumination of alkyl-substituted acetylenic alcohols (propargyl, homopropargyl, and bishomopropargyl alcohols) is not regioselective.

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2 citations

Dzhemileva Lilya

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DSc in Health sciences, associate professor

128 publications, 1 281 citations, 70 reviews

h-index: 21

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Institute of Physiologically Active Compounds of the Russian Academy of Science

Mendeleev University of Chemical Technology of Russia

Endocrinology Research Centre

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Ramazanov I. R., Kadikova R. N., Dzhemilev U. M. Cp2ZrCl2-Catalyzed cycloalumination of acetylenic alcohols and propargylamines by Et3Al // Russian Chemical Bulletin. 2011. Vol. 60. No. 1. pp. 99-106.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1007/s11172-011-0013-2

UR - https://doi.org/10.1007/s11172-011-0013-2

TI - Cp2ZrCl2-Catalyzed cycloalumination of acetylenic alcohols and propargylamines by Et3Al

T2 - Russian Chemical Bulletin

AU - Ramazanov, I R

AU - Kadikova, R N

AU - Dzhemilev, U M

PY - 2011

DA - 2011/01/01

PB - Springer Nature

SP - 99-106

IS - 1

VL - 60

SN - 1066-5285

SN - 1573-9171

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2011_Ramazanov,

author = {I R Ramazanov and R N Kadikova and U M Dzhemilev},

title = {Cp2ZrCl2-Catalyzed cycloalumination of acetylenic alcohols and propargylamines by Et3Al},

journal = {Russian Chemical Bulletin},

year = {2011},

volume = {60},

publisher = {Springer Nature},

month = {jan},

url = {https://doi.org/10.1007/s11172-011-0013-2},

number = {1},

pages = {99--106},

doi = {10.1007/s11172-011-0013-2}

}

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MLA Copy

Ramazanov, I. R., et al. “Cp2ZrCl2-Catalyzed cycloalumination of acetylenic alcohols and propargylamines by Et3Al.” Russian Chemical Bulletin, vol. 60, no. 1, Jan. 2011, pp. 99-106. https://doi.org/10.1007/s11172-011-0013-2.

Publisher

Springer Nature

Journal

Russian Chemical Bulletin

scimago Q3

SJR

0.305

CiteScore

2.8

Impact factor

—

ISSN

10665285 (Print)

15739171 (Electronic)