Acetyl-containing phosphine oxides as extractants for actinides and lanthanides
A M Safiulina
1
,
A G Matveeva
2
,
T K Dvoryanchikova
3
,
O A Sinegribova
3
,
A M Tu
3
,
D A Tatarinov
4
,
A A Kostin
4
,
V F Mironov
4
,
I. G. Tananaev
1
Publication type: Journal Article
Publication date: 2012-02-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Extraction capability and selectivity of acetyl-containing phosphine oxides R2P(O)CMe2CH2C(O)Me (R = Pr, Bu, n-C5H11, n-C6H13, n-C8H17, Ph) toward actinides (UVI, ThIV) and trivalent lanthanides (LaIII, NdIII, HoIII, YbIII) were studied. The new ligands were shown to be more efficient and selective in the extraction of uranium, thorium, and heavy lanthanides from nitric acid solutions into chloroform as compared to the known extractants such as carbamoylphosphine oxide Ph2P(O)CH2C(O)NBu2, trioctylphosphine oxide (n-C8H17)3P(O), and tributyl phosphate (n-BuO)3P(O).
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Total citations:
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GOST
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Safiulina A. M. et al. Acetyl-containing phosphine oxides as extractants for actinides and lanthanides // Russian Chemical Bulletin. 2012. Vol. 61. No. 2. pp. 392-398.
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Safiulina A. M., Matveeva A. G., Dvoryanchikova T. K., Sinegribova O. A., Tu A. M., Tatarinov D. A., Kostin A. A., Mironov V. F., Tananaev I. G. Acetyl-containing phosphine oxides as extractants for actinides and lanthanides // Russian Chemical Bulletin. 2012. Vol. 61. No. 2. pp. 392-398.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s11172-012-0055-0
UR - https://doi.org/10.1007/s11172-012-0055-0
TI - Acetyl-containing phosphine oxides as extractants for actinides and lanthanides
T2 - Russian Chemical Bulletin
AU - Safiulina, A M
AU - Matveeva, A G
AU - Dvoryanchikova, T K
AU - Sinegribova, O A
AU - Tu, A M
AU - Tatarinov, D A
AU - Kostin, A A
AU - Mironov, V F
AU - Tananaev, I. G.
PY - 2012
DA - 2012/02/01
PB - Springer Nature
SP - 392-398
IS - 2
VL - 61
SN - 1066-5285
SN - 1573-9171
ER -
Cite this
BibTex (up to 50 authors)
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@article{2012_Safiulina,
author = {A M Safiulina and A G Matveeva and T K Dvoryanchikova and O A Sinegribova and A M Tu and D A Tatarinov and A A Kostin and V F Mironov and I. G. Tananaev},
title = {Acetyl-containing phosphine oxides as extractants for actinides and lanthanides},
journal = {Russian Chemical Bulletin},
year = {2012},
volume = {61},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007/s11172-012-0055-0},
number = {2},
pages = {392--398},
doi = {10.1007/s11172-012-0055-0}
}
Cite this
MLA
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Safiulina, A. M., et al. “Acetyl-containing phosphine oxides as extractants for actinides and lanthanides.” Russian Chemical Bulletin, vol. 61, no. 2, Feb. 2012, pp. 392-398. https://doi.org/10.1007/s11172-012-0055-0.