Nitropyrazoles 20. Synthesis and transformations of 1-methoxymethyl-3,4,5-trinitropyrazole
Publication type: Journal Article
Publication date: 2012-02-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
1-Methoxymethyl-3,4,5-trinitropyrazole, synthesized from 3,4,5-trinitropyrazole by the action of methoxymethyl chloride, was involved into the nucleophilic substitution reaction with N-nucleophiles (aliphatic amines, hydrazine derivatives). The reaction was effected regioselectively with substitution of the nitro group at position 5 in good yields. The thus obtained 5-R-substituted compounds under acid hydrolysis conditions give N-unsubstituted 5-R-3,4-dinitropyrazoles.
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Total citations:
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Citations from 2025:
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(14.29%)
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Dalinger I. L. et al. Nitropyrazoles 20. Synthesis and transformations of 1-methoxymethyl-3,4,5-trinitropyrazole // Russian Chemical Bulletin. 2012. Vol. 61. No. 2. pp. 464-466.
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Dalinger I. L., Vatsadze I. A., Shkineva T., Popova G. P., Shevelev S. Nitropyrazoles 20. Synthesis and transformations of 1-methoxymethyl-3,4,5-trinitropyrazole // Russian Chemical Bulletin. 2012. Vol. 61. No. 2. pp. 464-466.
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TY - JOUR
DO - 10.1007/s11172-012-0065-y
UR - https://doi.org/10.1007/s11172-012-0065-y
TI - Nitropyrazoles 20. Synthesis and transformations of 1-methoxymethyl-3,4,5-trinitropyrazole
T2 - Russian Chemical Bulletin
AU - Dalinger, I L
AU - Vatsadze, I A
AU - Shkineva, T.K.
AU - Popova, G P
AU - Shevelev, S.A.
PY - 2012
DA - 2012/02/01
PB - Springer Nature
SP - 464-466
IS - 2
VL - 61
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2012_Dalinger,
author = {I L Dalinger and I A Vatsadze and T.K. Shkineva and G P Popova and S.A. Shevelev},
title = {Nitropyrazoles 20. Synthesis and transformations of 1-methoxymethyl-3,4,5-trinitropyrazole},
journal = {Russian Chemical Bulletin},
year = {2012},
volume = {61},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007/s11172-012-0065-y},
number = {2},
pages = {464--466},
doi = {10.1007/s11172-012-0065-y}
}
Cite this
MLA
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Dalinger, I. L., et al. “Nitropyrazoles 20. Synthesis and transformations of 1-methoxymethyl-3,4,5-trinitropyrazole.” Russian Chemical Bulletin, vol. 61, no. 2, Feb. 2012, pp. 464-466. https://doi.org/10.1007/s11172-012-0065-y.