Synthesis and transformations of metallacycles 40. Catalytic cycloalumination in the synthesis of 3-substituted phospholanes
Publication type: Journal Article
Publication date: 2012-08-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
An efficient one-pot method was developed for the synthesis of 3-alkyland 3-benzyl-substituted phospholanes through the successive Cp2ZrCl2-catalyzed cycloalumination of α-olefins in the presence of AlEt3 giving the corresponding aluminacyclopentanes followed by the in situ replacement of the aluminum atom in the latter compounds by a P atom by means of methyl(phenyl)dichlorophosphines. The oxidation of 3-alkyl- and 3-benzyl-1-methyl(phenyl)-phospholanes with hydrogen peroxide affords 3-alkyl- and 3-benzyl-1-methyl(phenyl)-phospholane 1-oxides, respectively.
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Total citations:
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Citations from 2024:
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(16.67%)
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GOST
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Dyakonov V. A. et al. Synthesis and transformations of metallacycles 40. Catalytic cycloalumination in the synthesis of 3-substituted phospholanes // Russian Chemical Bulletin. 2012. Vol. 61. No. 8. pp. 1556-1559.
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Dyakonov V. A., Makhamatkhanova A. L., Tyumkina T. V., Dzhemilev U. M. Synthesis and transformations of metallacycles 40. Catalytic cycloalumination in the synthesis of 3-substituted phospholanes // Russian Chemical Bulletin. 2012. Vol. 61. No. 8. pp. 1556-1559.
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RIS
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TY - JOUR
DO - 10.1007/s11172-012-0205-4
UR - https://doi.org/10.1007/s11172-012-0205-4
TI - Synthesis and transformations of metallacycles 40. Catalytic cycloalumination in the synthesis of 3-substituted phospholanes
T2 - Russian Chemical Bulletin
AU - Dyakonov, V A
AU - Makhamatkhanova, A L
AU - Tyumkina, T V
AU - Dzhemilev, U M
PY - 2012
DA - 2012/08/01
PB - Springer Nature
SP - 1556-1559
IS - 8
VL - 61
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2012_Dyakonov,
author = {V A Dyakonov and A L Makhamatkhanova and T V Tyumkina and U M Dzhemilev},
title = {Synthesis and transformations of metallacycles 40. Catalytic cycloalumination in the synthesis of 3-substituted phospholanes},
journal = {Russian Chemical Bulletin},
year = {2012},
volume = {61},
publisher = {Springer Nature},
month = {aug},
url = {https://doi.org/10.1007/s11172-012-0205-4},
number = {8},
pages = {1556--1559},
doi = {10.1007/s11172-012-0205-4}
}
Cite this
MLA
Copy
Dyakonov, V. A., et al. “Synthesis and transformations of metallacycles 40. Catalytic cycloalumination in the synthesis of 3-substituted phospholanes.” Russian Chemical Bulletin, vol. 61, no. 8, Aug. 2012, pp. 1556-1559. https://doi.org/10.1007/s11172-012-0205-4.